1,4-Benzenediamine, N,N,N',N'-tetramethyl-
- Formula: C10H16N2
- Molecular weight: 164.2474
- IUPAC Standard InChIKey: CJAOGUFAAWZWNI-UHFFFAOYSA-N
- CAS Registry Number: 100-22-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: p-Phenylenediamine, N,N,N',N'-tetramethyl-; p-Bis(dimethylamino)benzene; N,N,N',N'-Tetramethyl-p-phenylenediamine; N,N,N',N'-Tetramethyl-1,4-phenylenediamine; Tetramethyl-p-phenylenediamine; TMPD; N,N,N',N'-Tetramethyl-1,4-Benzenediamine; N,N,N',N,-Tetramethyl-p-phenylenediamine; Benzene, 1,4-bis(dimethylamino)-; 1,4-Bis(dimethylamino)benzene; N,N,N',N'-Tetramethyl-p-fenylendiamin; Tetramethyl-p-phenyldiamine; TL 85; Wurster's reagent; Wurster's blue; 1,4-Benzenediamine, N1,N1,N4,N4-tetramethyl-
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
6.1 ± 0.1 | PE | Egdell, Green, et al., 1975 | LLK |
6.20 ± 0.05 | PI | Adamchuk, Dmitriev, et al., 1972 | LLK |
≤6.20 ± 0.02 | PI | Nakato, Ozaki, et al., 1971 | LLK |
6.7 | CTS | Foster, 1959 | RDSH |
6.75 | PE | Kaim and Bock, 1978 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Egdell, Green, et al., 1975
Egdell, R.; Green, J.C.; Rao, C.N.R.,
Photoelectron spectra of substituted benzenes,
Chem. Phys. Lett., 1975, 33, 600. [all data]
Adamchuk, Dmitriev, et al., 1972
Adamchuk, V.K.; Dmitriev, A.B.; Prudnikova, G.V.; Sorokin, L.S.,
Photoionization of low-volatility molecules in a Geiger counter,
Opt. Spectrosc., 1972, 33, 191, In original 358. [all data]
Nakato, Ozaki, et al., 1971
Nakato, Y.; Ozaki, M.; Egawa, A.; Tsubornura, H.,
Organic amino compounds with very low ionization potentials,
Chem. Phys. Lett., 1971, 9, 615. [all data]
Foster, 1959
Foster, R.,
Ionization potentials of electron donors,
Nature (London), 1959, 183, 1253. [all data]
Kaim and Bock, 1978
Kaim, W.; Bock, H.,
R2P- und R2N-substituierte Benzole: Die Ladungsverteilung in ihren Kationen, Anionen und Trianionen,
Chem. Ber., 1978, 111, 3843. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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