Molybdenum tetrakis(dimethylamide)
- Formula: C8H24MoN4
- Molecular weight: 272.26
- CAS Registry Number: 100207-68-9
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 72. ± 6. | kJ/mol | C | Adedeji, Cavell, et al., 1979 | See also Pilcher and Skinner, 1983.; AC |
| ΔsubH° | 72.4 ± 6.0 | kJ/mol | RSC | Adedeji, Cavell, et al., 1979 | MS |
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 88. ± 3. | 376. | C | Adedeji, Cavell, et al., 1979 | AC |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 5.30 | PE | Chisholm, Cowley, et al., 1980 | Vertical value; LLK |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Adedeji, Cavell, et al., 1979
Adedeji, F.A.; Cavell, K.J.; Cavell, S.; Connor, J.A.; Skinner, H.A.; Zafarani-Moattar, M.T.,
J. Chem. Soc. Faraday Trans. 1, 1979, 75, 603. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Chisholm, Cowley, et al., 1980
Chisholm, M.H.; Cowley, A.H.; Lattman, M.,
A UV photoelectron spectroscopic investigation of the bonding in some tri-, tetra-, and penta- coordinated dialkylamino compounds of chromium, molybdenum, niobium, and tantalum,
J. Am. Chem. Soc., 1980, 102, 46. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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