CH3SiH


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Iron ion (1+) + CH4Si = (Iron ion (1+) • CH4Si)

By formula: Fe+ + CH4Si = (Fe+ • CH4Si)

Quantity Value Units Method Reference Comment
Δr280. ± 46.kJ/molICRJacobson and Bakhtiar, 1993gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Iron ion (1+) + CH4Si = (Iron ion (1+) • CH4Si)

By formula: Fe+ + CH4Si = (Fe+ • CH4Si)

Quantity Value Units Method Reference Comment
Δr280. ± 46.kJ/molICRJacobson and Bakhtiar, 1993gas phase

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txd = 30300 N2 Reisenauer, Mihm, et al., 1982
Maier, Mihm, et al., 1984

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Txd = 20800 Ar Reisenauer, Mihm, et al., 1982
Maier, Mihm, et al., 1984

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

2004 m Ar IR Reisenauer, Mihm, et al., 1982
Maier, Mihm, et al., 1984
1986 w N2 IR Reisenauer, Mihm, et al., 1982
Maier, Mihm, et al., 1984
1978 w N2 IR Reisenauer, Mihm, et al., 1982
Maier, Mihm, et al., 1984
1971 m N2 IR Reisenauer, Mihm, et al., 1982
Maier, Mihm, et al., 1984
1935 w Ar IR Reisenauer, Mihm, et al., 1982
Maier, Mihm, et al., 1984

Additional references: Jacox, 1994, page 309

Notes

wWeak
mMedium
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
dPhotodissociation threshold

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jacobson and Bakhtiar, 1993
Jacobson, D.B.; Bakhtiar, R., Generation, Characterization and Properties of Iron-Silylene and Iron-Sylene Cationic Complexes in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 23, 10830, https://doi.org/10.1021/ja00076a046 . [all data]

Reisenauer, Mihm, et al., 1982
Reisenauer, H.P.; Mihm, G.; Maier, G., Reversible Photoisomerisierung zwischen Silaethenen und Methylsilylenen (Methylsilandiylen), Angew. Chem., 1982, 94, 11, 864, https://doi.org/10.1002/ange.19820941110 . [all data]

Maier, Mihm, et al., 1984
Maier, G.; Mihm, G.; Reisenauer, H.P.; Littmann, D., Hetero-π-Systeme, 9. Über die Beziehungen zwischen Silaethenen und Methylsilylenen, Chem. Ber., 1984, 117, 7, 2369, https://doi.org/10.1002/cber.19841170709 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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