ScF3..F anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-1983. ± 15.kJ/molTherBoltalina, Borshchevskii, et al., 1992Critical review; value altered from reference due to conversion from electron convention to ion convention

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

F4Sc- + F3Sc = F7Sc2-

By formula: F4Sc- + F3Sc = F7Sc2-

Quantity Value Units Method Reference Comment
Δr228.0 ± 0.84kJ/molTDAsNikitin, Sidorov, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Δr198.7 ± 1.3kJ/molTDAsNikitin, Sidorov, et al., 1981gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

F4Sc- + F3Sc = F7Sc2-

By formula: F4Sc- + F3Sc = F7Sc2-

Quantity Value Units Method Reference Comment
Δr228.0 ± 0.84kJ/molTDAsNikitin, Sidorov, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Δr198.7 ± 1.3kJ/molTDAsNikitin, Sidorov, et al., 1981gas phase

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

f2 3 Asym. stretch 601.5 Ar IR Wang and Andrews, 2010


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Nikitin, Sidorov, et al., 1981
Nikitin, M.I.; Sidorov, L.N.; Skokan, E.V.; Sorokin, I.D., Mass spectrometric determination of the heats of formation of ScF4- and KF2-, Russ. J. Phys. Chem., 1981, 55, 1107. [all data]

Wang and Andrews, 2010
Wang, X.; Andrews, L., Infrared Spectra of MF, J. Phys. Chem. A, 2010, 114, 6, 2293, https://doi.org/10.1021/jp910936d . [all data]


Notes

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