anti-N3C(O)N

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 32470 Ne Zeng, Beckers, et al., 2011

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 30770 Ne Zeng, Beckers, et al., 2011

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 29070 Ne Zeng, Beckers, et al., 2011

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 23260 Ne Zeng, Beckers, et al., 2011

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 13275 Ne A-X 604 753 Zeng, Beckers, et al., 2011
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
466 Ar AB Zeng, Beckers, et al., 2011

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 N3 a-stretch 2159.9 s Ne IR Zeng, Beckers, et al., 2011
1 N3 a-stretch 2159.7 m s Ar IR Zeng, Beckers, et al., 2011
2 CO stretch 1582.5 m s Ne IR Zeng, Beckers, et al., 2011
2 CO stretch 1581.7 m Ar IR Zeng, Beckers, et al., 2011
3 N3 s-stretch 1204.0 vs Ne IR Zeng, Beckers, et al., 2011
3 N3 s-stretch 1209.1 vs Ar IR Zeng, Beckers, et al., 2011
4 CN stretch 1138.8 w m Ne IR Zeng, Beckers, et al., 2011
4 CN stretch 1138.5 w Ar IR Zeng, Beckers, et al., 2011
5 C-N3 stretch 897.6 w Ne IR Zeng, Beckers, et al., 2011
5 C-N3 stretch 894.6 w Ar IR Zeng, Beckers, et al., 2011
6 N3 deformation 662.7 w m Ne IR Zeng, Beckers, et al., 2011
6 N3 deformation 664.8 w m Ar IR Zeng, Beckers, et al., 2011
a 10 N2CO OPLA 651.8 w m Ne IR Zeng, Beckers, et al., 2011
10 N2CO OPLA 646.5 w m Ar IR Zeng, Beckers, et al., 2011

Notes

wWeak
mMedium
sStrong
vsVery strong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zeng, Beckers, et al., 2011
Zeng, X.; Beckers, H.; Willner, H., Matrix Isolation of Two Isomers of N4CO, Angew. Chem. Int. Ed., 2011, 50, 2, 482, https://doi.org/10.1002/anie.201005177 . [all data]

Notes

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