PNS


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Td = 39400 U Ar Zeng, Beckers, et al., 2012

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Σ+ 1 PN stretch 1374.1 vs Ar IR Zeng, Beckers, et al., 2012
Π 2 Bend 358.1 w Ar IR Zeng, Beckers, et al., 2012
2 Bend 354.4 Ar IR Zeng, Beckers, et al., 2012
Σ+ 3 NS stretch 641.2 w Ar IR Zeng, Beckers, et al., 2012

Notes

wWeak
vsVery strong
UUpper bound
dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zeng, Beckers, et al., 2012
Zeng, X.; Beckers, H.; Willner, H.; Francisco, J.S., Experimental Observation of the 16-Electron Molecules SPN, SNP, and Cyclic PSN, Angew. Chem. Int. Ed., 2012, 51, 14, 3334, https://doi.org/10.1002/anie.201108636 . [all data]


Notes

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