cis-CH3CHCHO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 29090.1 ± 0.5 gas B-X 330 347 Williams, Zingher, et al., 1998
Washida, Inomata, et al., 1998

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 9416 ± 16 gas Alconcel, Deyerl, et al., 2001
Yacovitch, Kim, et al., 2011
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 7 1618 gas PE Yacovitch, Kim, et al., 2011
5 1363 gas PE Yacovitch, Kim, et al., 2011
10 1053 gas PE Yacovitch, Kim, et al., 2011

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 5 1578 gas PE Yacovitch, Kim, et al., 2011
6 1402 gas PE Yacovitch, Kim, et al., 2011
1199 gas PE Yacovitch, Kim, et al., 2011
10 1161 gas PE Yacovitch, Kim, et al., 2011
13 695 gas PE Yacovitch, Kim, et al., 2011
14 293 gas PE Yacovitch, Kim, et al., 2011
a 19 CH wag 620 gas PE Yacovitch, Kim, et al., 2011

Additional references: Jacox, 2003, page 390

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Williams, Zingher, et al., 1998
Williams, S.; Zingher, E.; Weisshaar, J.C., B ← X Vibronic Spectra and B-State Fluorescence Lifetimes of Methylvinoxy Isomers, J. Phys. Chem. A, 1998, 102, 13, 2297, https://doi.org/10.1021/jp980451u . [all data]

Washida, Inomata, et al., 1998
Washida, N.; Inomata, S.; Furubayashi, M., Laser-Induced Fluorescence of Methyl Substituted Vinoxy Radicals and Reactions of Oxygen Atoms with Olefins, J. Phys. Chem. A, 1998, 102, 41, 7924, https://doi.org/10.1021/jp9822586 . [all data]

Alconcel, Deyerl, et al., 2001
Alconcel, L.S.; Deyerl, H.-J.; Continetti, R.E., Effects of Alkyl Substitution on the Energetics of Enolate Anions and Radicals, J. Am. Chem. Soc., 2001, 123, 50, 12675, https://doi.org/10.1021/ja0120431 . [all data]

Yacovitch, Kim, et al., 2011
Yacovitch, T.I.; Kim, J.B.; Garand, E.; van der Poll, D.G.; Neumark, D.M., Slow photoelectron velocity-map imaging spectroscopy of the n-methylvinoxide anion, J. Chem. Phys., 2011, 134, 13, 134307, https://doi.org/10.1063/1.3572269 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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