cum-C14H-

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 23763 ± 10 gas A-X 369 421 Kirkwood, Tulej, et al., 1999
To = 23837 ± 15 Ne A-X 361 420 Kirkwood, Tulej, et al., 1999
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
CC stretch 1996 ± 15 gas MPD Kirkwood, Tulej, et al., 1999
CC stretch 1982 ± 20 Ne AB Kirkwood, Tulej, et al., 1999
C=C stretch 1747 ± 15 gas MPD Kirkwood, Tulej, et al., 1999
C-C stretch 1280 ± 15 gas MPD Kirkwood, Tulej, et al., 1999
C-C stretch 1244 ± 20 Ne AB Kirkwood, Tulej, et al., 1999

Additional references: Jacox, 2003, page 383

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kirkwood, Tulej, et al., 1999
Kirkwood, D.A.; Tulej, M.; Pachkov, M.V.; Schnaiter, M.; Guthe, F.; Grutter, M.; Wyss, M.; Maier, J.P.; Fischer, G., Electronic spectra of carbon chain anions: C[sub 2n]H[sup -] (n=5--12), J. Chem. Phys., 1999, 111, 20, 9280, https://doi.org/10.1063/1.479842 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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