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D2CI+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   a


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 15289.4 gas a-X 580 660 Tao, Mukarakate, et al., 2006
Tao, Mukarakate, et al., 2007

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 CD2 scissors 1043 ± 2 gas LF Tao, Mukarakate, et al., 2006
Tao, Mukarakate, et al., 2007
3 CI stretch 689 ± 2 gas LF Tao, Mukarakate, et al., 2006
Tao, Mukarakate, et al., 2007
b1 4 OPLA 747 H gas LF Tao, Mukarakate, et al., 2007
b2 6 Deform. 664 H gas LF Tao, Mukarakate, et al., 2007

Notes

H(1/2)(2nu)
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Tao, Mukarakate, et al., 2006
Tao, C.; Mukarakate, C.; Reid, S.A., Laser Spectroscopy of a Halocarbocation in the Gas Phase: CH, J. Am. Chem. Soc., 2006, 128, 29, 9320, https://doi.org/10.1021/ja0631293 . [all data]

Tao, Mukarakate, et al., 2007
Tao, C.; Mukarakate, C.; Mishchenko, Y.; Brusse, D.; Reid, S.A., Electronic Spectroscopy of an Isolated Halocarbocation: The Iodomethyl Cation CH, J. Phys. Chem. A, 2007, 111, 42, 10562, https://doi.org/10.1021/jp0749322 . [all data]


Notes

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