t-CH3C-OCH3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 25600 N2 Sheridan, Moss, et al., 1988

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1330 N2 IR Sheridan, Moss, et al., 1988
1288 N2 IR Sheridan, Moss, et al., 1988
1160 N2 IR Sheridan, Moss, et al., 1988
1100 N2 IR Sheridan, Moss, et al., 1988
550 N2 IR Sheridan, Moss, et al., 1988

Additional references: Jacox, 1994, page 415

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sheridan, Moss, et al., 1988
Sheridan, R.S.; Moss, R.A.; Wilk, B.K., et al., Direct observational studies of a singlet alkylcarbene: methylmethoxycarbene, a remarkably selective nucleophile, J. Am. Chem. Soc., 1988, 110, 22, 7563, https://doi.org/10.1021/ja00230a061 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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