c-HOCO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 OH stretch 3411.2 N2 IR Mielke, Olbert-Majkut, et al., 2003
1 OH stretch 3316 w m CO IR Milligan and Jacox, 1971
2 C=O stretch 1802.1 N2 IR Mielke, Olbert-Majkut, et al., 2003
2 C=O stretch 1797 s CO IR Milligan and Jacox, 1971
3 HOC bend 1290 ± 10 gas PE Johnson, Poad, et al., 2011
3 HOC bend 1261 s CO IR Milligan and Jacox, 1971
4 C-O stretch 1040 ± 10 gas PE Johnson, Poad, et al., 2011
4 C-O stretch 1062.8 N2 IR Mielke, Olbert-Majkut, et al., 2003
4 C-O stretch 1088 s CO IR Milligan and Jacox, 1971
5 OCO bend 605 ± 5 gas PE Johnson, Poad, et al., 2011
5 OCO bend 620 m CO IR Milligan and Jacox, 1971

Additional references: Jacox, 1994, page 167; Oyama, Funato, et al., 2011

Notes

wWeak
mMedium
sStrong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mielke, Olbert-Majkut, et al., 2003
Mielke, Z.; Olbert-Majkut, A.; Tokhadze, K.G., Photolysis of the OC...HONO complex in low temperature matrices: Infrared detection and ab initio calculations of nitrosoformic acid, HOC(O)NO, J. Chem. Phys., 2003, 118, 3, 1364, https://doi.org/10.1063/1.1528897 . [all data]

Milligan and Jacox, 1971
Milligan, D.E.; Jacox, M.E., Infrared Spectrum and Structure of Intermediates in the Reaction of OH with CO, J. Chem. Phys., 1971, 54, 3, 927, https://doi.org/10.1063/1.1675022 . [all data]

Johnson, Poad, et al., 2011
Johnson, C.J.; Poad, M.E. Harding.B.L.J.; Stanton, J.F.; Continetti, R.E., Electron Affinities, Well Depths, and Vibrational Spectroscopy of, J. Am. Chem. Soc., 2011, 133, 49, 19606, https://doi.org/10.1021/ja207724f . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Oyama, Funato, et al., 2011
Oyama, T.; Funato, W.; Sumiyoshi, Y.; Endo, Y., Observation of the pure rotational spectra of trans- and cis-HOCO, J. Chem. Phys., 2011, 134, 17, 174303, https://doi.org/10.1063/1.3578179 . [all data]

Notes

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