C6H5CD2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 13 Ring deform. 500 T gas PE TPE Houle and Beauchamp, 1978
Eiden, Weinhold, et al., 1991
Eiden, Lu, et al., 1996
a2 17 278 H gas TPE Eiden, Lu, et al., 1996
b1 23 349 T gas TPE Eiden, Lu, et al., 1996
24 145 T gas TPE Eiden, Lu, et al., 1996
b2 32 880 T gas TPE Eiden, Lu, et al., 1996
33 862 T gas TPE Eiden, Lu, et al., 1996
34 779 T gas TPE Eiden, Lu, et al., 1996
35 Ring deform. 575 ± 2 gas TPE Eiden, Weinhold, et al., 1991
Eiden, Lu, et al., 1996
36 302 ± 2 gas TPE Eiden, Lu, et al., 1996

Notes

H(1/2)(2ν)
TTentative assignment or approximate value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Houle and Beauchamp, 1978
Houle, F.A.; Beauchamp, J.L., Detection and investigation of allyl and benzyl radicals by photoelectron spectroscopy, J. Am. Chem. Soc., 1978, 100, 3290. [all data]

Eiden, Weinhold, et al., 1991
Eiden, G.C.; Weinhold, F.; Weisshar, J.C., Photoelectron spectroscopy of free radicals with cm-1 resolution: The benzyl cation, J. Chem. Phys., 1991, 95, 8665. [all data]

Eiden, Lu, et al., 1996
Eiden, G.C.; Lu, K.-T.; Badenhoop, J.; Weinhold, F.; Weisshaar, J.C., Threshold photoionization spectra of benzyl radical: Cation vibrational states and ab initio calculations, J. Chem. Phys., 1996, 104, 22, 8886, https://doi.org/10.1063/1.471624 . [all data]

Notes

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