CD3HgD
- Formula: CD4Hg
- Molecular weight: 220.66
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | CD3 stretch | 2127.7 | w | Ar | IR | Legay-Sommaire and Legay, 1994 Greene, Andrews, et al., 1995 |
2 | HgD stretch | 1400.7 | vs | Ar | IR | Legay-Sommaire and Legay, 1994 Greene, Andrews, et al., 1995 | |
2 | HgD stretch | 1402.6 | N2 | IR | Legay-Sommaire and Legay, 1996 | ||
3 | CD3 deform. | 1024.5 | w T | Ar | IR | Legay-Sommaire and Legay, 1994 | |
4 | HgC stretch | 487.0 | Ar | IR | Greene, Andrews, et al., 1995 | ||
4 | HgC stretch | 485.6 | N2 | IR | Legay-Sommaire and Legay, 1996 | ||
e | 5 | CD3 stretch | 2233.9 | m | Ar | IR | Legay-Sommaire and Legay, 1994 |
6 | CD3 deform. | 1041.1 | w T | Ar | IR | Legay-Sommaire and Legay, 1994 Greene, Andrews, et al., 1995 | |
7 | CD3 rock | 593.5 | m | Ar | IR | Legay-Sommaire and Legay, 1994 Greene, Andrews, et al., 1995 | |
7 | CD3 rock | 592.1 | Ar | IR | Legay-Sommaire and Legay, 1994 Greene, Andrews, et al., 1995 | ||
7 | CD3 rock | 592.8 | N2 | IR | Legay-Sommaire and Legay, 1996 | ||
7 | CD3 rock | 589.3 | N2 | IR | Legay-Sommaire and Legay, 1996 | ||
8 | CHgD deform. | 374.5 | Ar | IR | Greene, Andrews, et al., 1995 | ||
Notes
w | Weak |
m | Medium |
vs | Very strong |
T | Tentative assignment or approximate value |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Legay-Sommaire and Legay, 1994
Legay-Sommaire, N.; Legay, F.,
Photochemical formation of CH3HgH in Hg/CH4/Ar matrices studied by FTIR spectroscopy,
Chem. Phys. Lett., 1994, 217, 1-2, 97, https://doi.org/10.1016/0009-2614(93)E1367-P
. [all data]
Greene, Andrews, et al., 1995
Greene, T.M.; Andrews, L.; Downs, A.J.,
The Reaction of Zinc, Cadmium, and Mercury Atoms with Methane: Infrared Spectra of the Matrix-Isolated Methylmetal Hydrides,
J. Am. Chem. Soc., 1995, 117, 31, 8180, https://doi.org/10.1021/ja00136a015
. [all data]
Legay-Sommaire and Legay, 1996
Legay-Sommaire, N.; Legay, F.,
Isotope effects in the photochemical formation of HHgCH3 and DHgCD3 in nitrogen and methane matrices,
Chem. Phys., 1996, 211, 1-3, 367, https://doi.org/10.1016/0301-0104(96)00190-5
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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