CD2NO2

Formula: CD₂NO₂
Molecular weight: 62.0444
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Vibrational and/or electronic energy levels

State: X

Vib. sym.	No.	Approximate type of mode	cm^-1		Med.	Method	References


a₁	2	NO₂ s-stretch	1292 ± 25		gas	PE	Metz, Cyr, et al., 1991
	2	NO₂ s-stretch	1296	vs H	Ar	IR	Jacox, 1983 Jacox, 1987
	4	Mixed	906	m H	Ar	IR	Jacox, 1983 Jacox, 1987
	5	NO₂ scissors	668	H	Ar	IR	Jacox, 1983 Jacox, 1987
a₂	6	Torsion	140	H	gas	PE	Metz, Cyr, et al., 1991
b₁	7	CNO₂ OPLA	694	m H	Ar	IR	Jacox, 1983 Jacox, 1987
b₂	10	NO₂ a-stretch	1460	vs H	Ar	IR	Jacox, 1983 Jacox, 1987

Notes

Medium

Very strong

(1/2)(2ν)

References

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Metz, Cyr, et al., 1991
Metz, R.B.; Cyr, D.R.; Neumark, D.M., Study of the 2B1 and 2A2 States of CH2NO2 via Ultraviolet Photoelectron Spectroscopy of the CH2NO2- Anion, J. Phys. Chem., 1991, 95, 7, 2900, https://doi.org/10.1021/j100160a047 . [all data]

Jacox, 1983
Jacox, M.E., Reaction of fluorine atoms with nitromethane. Vibrational spectra of the addition complex and of the nitromethyl free radical, J. Phys. Chem., 1983, 87, 16, 3126, https://doi.org/10.1021/j100239a034 . [all data]

Jacox, 1987
Jacox, M.E., Analysis of the vibrational spectrum of the nitromethyl free radical, J. Phys. Chem., 1987, 91, 19, 5038, https://doi.org/10.1021/j100303a030 . [all data]

Notes

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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