CD2NO2


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 NO2 s-stretch 1292 ± 25 gas PE Metz, Cyr, et al., 1991
2 NO2 s-stretch 1296 vs H Ar IR Jacox, 1983
Jacox, 1987
4 Mixed 906 m H Ar IR Jacox, 1983
Jacox, 1987
5 NO2 scissors 668 H Ar IR Jacox, 1983
Jacox, 1987
a2 6 Torsion 140 H gas PE Metz, Cyr, et al., 1991
b1 7 CNO2 OPLA 694 m H Ar IR Jacox, 1983
Jacox, 1987
b2 10 NO2 a-stretch 1460 vs H Ar IR Jacox, 1983
Jacox, 1987

Notes

mMedium
vsVery strong
H(1/2)(2nu)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Metz, Cyr, et al., 1991
Metz, R.B.; Cyr, D.R.; Neumark, D.M., Study of the 2B1 and 2A2 States of CH2NO2 via Ultraviolet Photoelectron Spectroscopy of the CH2NO2- Anion, J. Phys. Chem., 1991, 95, 7, 2900, https://doi.org/10.1021/j100160a047 . [all data]

Jacox, 1983
Jacox, M.E., Reaction of fluorine atoms with nitromethane. Vibrational spectra of the addition complex and of the nitromethyl free radical, J. Phys. Chem., 1983, 87, 16, 3126, https://doi.org/10.1021/j100239a034 . [all data]

Jacox, 1987
Jacox, M.E., Analysis of the vibrational spectrum of the nitromethyl free radical, J. Phys. Chem., 1987, 91, 19, 5038, https://doi.org/10.1021/j100303a030 . [all data]


Notes

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