cyc-C2D2S
- Formula: C2D2S
- Molecular weight: 60.115
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | CD stretch | 2485 | w | Ar | IR | Krantz and Laureni, 1977 Torres, Safarik, et al., 1979 Krantz and Laureni, 1981 |
2 | C=C stretch | 1567 | w | Ar | IR | Krantz and Laureni, 1977 Torres, Safarik, et al., 1979 Krantz and Laureni, 1981 | |
3 | C-S stretch | 681 | m | Ar | IR | Torres, Safarik, et al., 1979 | |
b1 | 6 | OPLA | 423 | m | Ar | IR | Krantz and Laureni, 1977 Torres, Safarik, et al., 1979 Krantz and Laureni, 1981 |
b2 | 7 | CD stretch | 2355 | m | Ar | IR | Torres, Safarik, et al., 1979 |
8 | CD deform. | 716 | s | Ar | IR | Torres, Safarik, et al., 1979 Krantz and Laureni, 1981 | |
Notes
w | Weak |
m | Medium |
s | Strong |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Krantz and Laureni, 1977
Krantz, A.; Laureni, J.,
A methodology for the preparation and characterization of three-membered, potentially antiaromatic molecules. Preparation of matrix-isolated thiirene and selenirene,
J. Am. Chem. Soc., 1977, 99, 14, 4842, https://doi.org/10.1021/ja00456a060
. [all data]
Torres, Safarik, et al., 1979
Torres, M.; Safarik, I.; Clement, A.; Bertie, J.E.; Strausz, O.P.,
Nouv. J. Chim., 1979, 3, 365. [all data]
Krantz and Laureni, 1981
Krantz, A.; Laureni, J.,
Characterization of matrix-isolated antiaromatic three-membered heterocycles. Preparation of the elusive thiirene molecule,
J. Am. Chem. Soc., 1981, 103, 3, 486, https://doi.org/10.1021/ja00393a002
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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