cyc-C2D2S


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CD stretch 2485 w Ar IR Krantz and Laureni, 1977
Torres, Safarik, et al., 1979
Krantz and Laureni, 1981
2 C=C stretch 1567 w Ar IR Krantz and Laureni, 1977
Torres, Safarik, et al., 1979
Krantz and Laureni, 1981
3 C-S stretch 681 m Ar IR Torres, Safarik, et al., 1979
b1 6 OPLA 423 m Ar IR Krantz and Laureni, 1977
Torres, Safarik, et al., 1979
Krantz and Laureni, 1981
b2 7 CD stretch 2355 m Ar IR Torres, Safarik, et al., 1979
8 CD deform. 716 s Ar IR Torres, Safarik, et al., 1979
Krantz and Laureni, 1981

Notes

wWeak
mMedium
sStrong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Krantz and Laureni, 1977
Krantz, A.; Laureni, J., A methodology for the preparation and characterization of three-membered, potentially antiaromatic molecules. Preparation of matrix-isolated thiirene and selenirene, J. Am. Chem. Soc., 1977, 99, 14, 4842, https://doi.org/10.1021/ja00456a060 . [all data]

Torres, Safarik, et al., 1979
Torres, M.; Safarik, I.; Clement, A.; Bertie, J.E.; Strausz, O.P., Nouv. J. Chim., 1979, 3, 365. [all data]

Krantz and Laureni, 1981
Krantz, A.; Laureni, J., Characterization of matrix-isolated antiaromatic three-membered heterocycles. Preparation of the elusive thiirene molecule, J. Am. Chem. Soc., 1981, 103, 3, 486, https://doi.org/10.1021/ja00393a002 . [all data]


Notes

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