CD2F2+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 CF2 stretch 970 ± 80 gas PE Brundle, Robin, et al., 1970
4 CF2 scissors 500 ± 80 gas PE Brundle, Robin, et al., 1970

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CD stretch 2062 m Ar IR Andrews and Prochaska, 1979
b1 7 980 w Ar IR Andrews and Prochaska, 1979
b2 8 CD2 wag 1063 s Ar IR Andrews and Prochaska, 1979
9 CF stretch 1262 vs Ar IR Andrews and Prochaska, 1979

Notes

wWeak
mMedium
sStrong
vsVery strong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brundle, Robin, et al., 1970
Brundle, C.R.; Robin, M.B.; Basch, H., Electronic energies and electronic structures of the fluoromethanes, J. Chem. Phys., 1970, 53, 2196. [all data]

Andrews and Prochaska, 1979
Andrews, L.; Prochaska, F.T., Infrared spectra of the CH2F2+, CHF2+, CHF+, and FH-- (CHF)- molecular ions in solid argon, J. Chem. Phys., 1979, 70, 10, 4714, https://doi.org/10.1063/1.437259 . [all data]


Notes

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