DCCAl

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 28806.9 gas A-X 328 354 Apetrei, Ding, et al., 2007
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 3 AlC stretch 628.5 gas MPI Apetrei, Ding, et al., 2007
Π 4 DCC bend 296.9 gas MPI Apetrei, Ding, et al., 2007
5 CCAl bend 115 gas MPI Apetrei, Ding, et al., 2007
5 CCAl bend 36.4 gas MPI Apetrei, Ding, et al., 2007

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 2 CC stretch 1860.8 Ar IR Burkholder and Andrews, 1993
3 AlC stretch 513.6 gas MPI Apetrei, Ding, et al., 2007
3 AlC stretch 505.2 Ar IR Burkholder and Andrews, 1993
Π 4 DCC deform. 229.7 gas MPI Apetrei, Ding, et al., 2007
4 DCC deform. 228 H Ar IR Burkholder and Andrews, 1993

Notes

H(1/2)(2ν)
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Apetrei, Ding, et al., 2007
Apetrei, C.; Ding, H.; Maier, J.P., Gas phase electronic spectrum of linear AlCCH, Phys. Chem. Chem. Phys., 2007, 9, 29, 3897, https://doi.org/10.1039/b706384a . [all data]

Burkholder and Andrews, 1993
Burkholder, T.R.; Andrews, L., Matrix infrared spectra of aluminum, gallium, and indium complexes with acetylene, Inorg. Chem., 1993, 32, 11, 2491, https://doi.org/10.1021/ic00063a048 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References