DBF2
- Formula: BDF2
- Molecular weight: 50.822
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a1 | 1 | BD stretch | 1960.0 ± 0.5 | gas | IR | Perec and Becka, 1965 Lynds and Bass, 1965 Porter and Wason, 1965 | |
| 1 | BD stretch | 1980 | N2 | IR | Shirk and Shirk, 1983 | ||
| 2 | BF2 s-stretch | 1126.4 ± 0.5 | gas | IR | Perec and Becka, 1965 Lynds and Bass, 1965 Porter and Wason, 1965 | ||
| 2 | BF2 s-stretch | 1121.3 | N2 | IR | Shirk and Shirk, 1983 | ||
| 3 | BF2 scissors | 540 | gas | IR | Perec and Becka, 1965 Porter and Wason, 1965 | ||
| b1 | 4 | OPLA | 785 | gas | IR | Perec and Becka, 1965 Porter and Wason, 1965 | |
| 4 | OPLA | 772.7 | N2 | IR | Shirk and Shirk, 1983 | ||
| b2 | 5 | BF2 a-stretch | 1392 | gas | IR | Perec and Becka, 1965 Porter and Wason, 1965 | |
| 5 | BF2 a-stretch | 1374.5 | N2 | IR | Shirk and Shirk, 1983 | ||
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Perec and Becka, 1965
Perec, M.; Becka, L.N.,
Infrared Spectra of Difluoroborane and Difluoroborane-d,
J. Chem. Phys., 1965, 43, 2, 721, https://doi.org/10.1063/1.1696796
. [all data]
Lynds and Bass, 1965
Lynds, L.; Bass, C.D.,
Vibrational---Rotational Spectrum of Difluoroborane and Difluoroborane-d,
J. Chem. Phys., 1965, 43, 12, 4357, https://doi.org/10.1063/1.1696697
. [all data]
Porter and Wason, 1965
Porter, R.F.; Wason, S.K.,
Reaction of Boroxine with BF3(g). Infrared Spectrum and Stability of HBF2(g),
J. Phys. Chem., 1965, 69, 7, 2208, https://doi.org/10.1021/j100891a010
. [all data]
Shirk and Shirk, 1983
Shirk, A.E.; Shirk, J.S.,
Matrix isolation-mass spectroscopy study of the reaction of boron trifluoride with trimethylamine-alane and trimethylamine-gallane,
Inorg. Chem., 1983, 22, 1, 72, https://doi.org/10.1021/ic00143a018
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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