DFCN
- Formula: CDFN
- Molecular weight: 47.0299
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a' | 1 | CD stretch | 2252 | w | Ar | IR | Hunt and Andrews, 1987 Misochko, Goldschleger, et al., 2001 Misochko, Akimov, et al., 2002 |
| 2 | C=N stretch | 1650 | m | Ar | IR | Hunt and Andrews, 1987 Misochko, Goldschleger, et al., 2001 Misochko, Akimov, et al., 2002 | |
| 3 | CF stretch | 1047 | vs | Ar | IR | Hunt and Andrews, 1987 Misochko, Goldschleger, et al., 2001 Misochko, Akimov, et al., 2002 | |
| 4 | DCF deform. | 911 | w | Ar | IR | Misochko, Akimov, et al., 2002 | |
| 5 | FCN bend | 530 | w m | Ar | IR | Hunt and Andrews, 1987 Misochko, Goldschleger, et al., 2001 Misochko, Akimov, et al., 2002 | |
| a | 6 | OPLA | 735 | w | Ar | IR | Misochko, Goldschleger, et al., 2001 Misochko, Akimov, et al., 2002 |
Notes
| w | Weak |
| m | Medium |
| vs | Very strong |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunt and Andrews, 1987
Hunt, R.D.; Andrews, L.,
FTIR spectra of photolytic reactions on cyanic acid with molecular fluorine in solid argon,
Inorg. Chem., 1987, 26, 18, 3051, https://doi.org/10.1021/ic00265a025
. [all data]
Misochko, Goldschleger, et al., 2001
Misochko, E.Ya.; Goldschleger, I.U.; Akimov, A.V.; Wight, C.A.,
Infrared and EPR Spectroscopic Observation of Novel Open-Shell Species: The Fluoroiminomethyl Radical (FC,
J. Am. Chem. Soc., 2001, 123, 21, 5156, https://doi.org/10.1021/ja015874f
. [all data]
Misochko, Akimov, et al., 2002
Misochko, E.Ya.; Akimov, A.V.; Goldschleger, I.U.; Wight, C.A.,
HFCN open-shell isomers in solid argon. I. Spectroscopy of the ground and excited states of HFC[Double Bond]N radical,
J. Chem. Phys., 2002, 116, 23, 10307, https://doi.org/10.1063/1.1477177
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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