D2CCl

Formula: CD₂Cl
Molecular weight: 51.492
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Vibrational and/or electronic energy levels

State: X

Vib. sym.	No.	Approximate type of mode	cm^-1		Med.	Method	References


a₁	2	CD₂ scissors	1045	m	Ar	IR	Jacox and Milligan, 1970 Andrews and Smith, 1970
	3	CCl stretch	788	m	Ar	IR	Jacox and Milligan, 1970 Andrews and Smith, 1970 Fridgen, Zhang, et al., 2000
	3	CCl stretch	791		Kr	IR	Fridgen, Zhang, et al., 2000
	3	CCl stretch	793		Xe	IR	Fridgen, Zhang, et al., 2000
b₁	4	OPLA	291	m	Ar	IR	Jacox and Milligan, 1970 Andrews and Smith, 1970

Notes

Medium

References

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Jacox and Milligan, 1970
Jacox, M.E.; Milligan, D.E., Matrix-Isolation Study of the Vacuum-Ultraviolet Photolysis of Methyl Chloride and Methylene Chloride. Infrared and Ultraviolet Spectra of the Free Radicals CCl, H2CCl, and CCl2, J. Chem. Phys., 1970, 53, 7, 2688, https://doi.org/10.1063/1.1674392 . [all data]

Andrews and Smith, 1970
Andrews, L.; Smith, D.W., Matrix Infrared Spectrum and Bonding in the Monochloromethyl Radical, J. Chem. Phys., 1970, 53, 7, 2956, https://doi.org/10.1063/1.1674422 . [all data]

Fridgen, Zhang, et al., 2000
Fridgen, T.D.; Zhang, X.K.; Parnis, J.M.; March, R.E., Isomerization and Fragmentation Products of CH, J. Phys. Chem. A, 2000, 104, 16, 3487, https://doi.org/10.1021/jp993162u . [all data]

Notes

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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