D2CBr+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CD2 s-stretch 2209.6 w m Ar IR Ma, Chen, et al., 2009
2 CD2 scissor 1130 ± 30 gas PE Andrews, Dyke, et al., 1984
2 CD2 scissor 1075.6 w m Ar IR Ma, Chen, et al., 2009
3 CBr stretch 780 ± 30 gas PE Andrews, Dyke, et al., 1984
3 CBr stretch 791.1 vs Ar IR Ma, Chen, et al., 2009
3 CBr stretch 787 Ar IR George, Kalume, et al., 2010
b1 4 CD2 wag 801.8 s Ar IR Ma, Chen, et al., 2009
b2 5 CD2 a-stretch 2366.3 vs Ar IR Ma, Chen, et al., 2009

Notes

wWeak
mMedium
sStrong
vsVery strong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ma, Chen, et al., 2009
Ma, R.; Chen, M.; Zhou, M., Infrared Spectra of the Chloromethyl and Bromomethyl Cations in Solid Argon, J. Phys. Chem. A, 2009, 113, 46, 12926, https://doi.org/10.1021/jp9084266 . [all data]

Andrews, Dyke, et al., 1984
Andrews, L.; Dyke, J.M.; Jonathan, N.; Keddar, N.; orris, A., The first bands in the photoelectron spectra of the CH2Br, CD2Br, CHBr2, and CH2I free radicals, J. Phys. Chem., 1984, 88, 1950. [all data]

George, Kalume, et al., 2010
George, L.; Kalume, A.; Reid, S.A., Pulsed-jet discharge matrix isolation and computational study of CX2Br+ (X=H, F), Chem. Phys. Lett., 2010, 484, 4-6, 214, https://doi.org/10.1016/j.cplett.2009.11.040 . [all data]

Notes

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