BrDBr-

Vibrational and/or electronic energy levels

Vib. sym.	No.	Approximate type of mode	cm^-1		Med.	Method	References


Σ_g⁺	1	Sym. stretch	163.9	T	Ne	IR	Lugez, Jacox, et al., 1996
	1	Sym. stretch	160.8	T	Ne	IR	Lugez, Jacox, et al., 1996
	1	Sym. stretch	170	T	Ar	IR	Bondybey, Pimentel, et al., 1971 Milligan and Jacox, 1971
	1	Sym. stretch	163.8	T	Kr	IR	Rasanen, Seetula, et al., 1993
	1	Sym. stretch	157.9	T	Kr	IR	Rasanen, Seetula, et al., 1993
Σ_u⁺	3	Asym. stretch	516.5		Ne	IR	Lugez, Jacox, et al., 1996
	3	Asym. stretch	510.7		Ne	IR	Lugez, Jacox, et al., 1996
	3	Asym. stretch	507.6		Ne	IR	Lugez, Jacox, et al., 1996
	3	Asym. stretch	498	s	Ar	IR	Bondybey, Pimentel, et al., 1971 Milligan and Jacox, 1971
	3	Asym. stretch	465.5		Kr	IR	Rasanen, Seetula, et al., 1993
	3	Asym. stretch	434.6		Xe	IR	Rasanen, Seetula, et al., 1993

Strong

Tentative assignment or approximate value

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Lugez, Jacox, et al., 1996
Lugez, C.L.; Jacox, M.E.; Thompson, W.E., The vibrational spectra of molecular ions isolated in solid neon. XIII. Ions derived from HBr and HI, J. Chem. Phys., 1996, 105, 10, 3901, https://doi.org/10.1063/1.472262 . [all data]

Bondybey, Pimentel, et al., 1971
Bondybey, V.; Pimentel, G.C.; Noble, P.N., Hydrogen Dibromide Radical: Infrared Detection through the Matrix Isolation Technique, J. Chem. Phys., 1971, 55, 2, 540, https://doi.org/10.1063/1.1675785 . [all data]

Milligan and Jacox, 1971
Milligan, D.E.; Jacox, M.E., Infrared Spectrum of the BrHBr- Ion Isolated in an Argon Matrix, J. Chem. Phys., 1971, 55, 5, 2550, https://doi.org/10.1063/1.1676447 . [all data]

Rasanen, Seetula, et al., 1993
Rasanen, M.; Seetula, J.; Kunttu, H., Photogeneration of ions via delocalized charge transfer states. II. HX2- (X=Cl,Br,I) in rare gas matrices, J. Chem. Phys., 1993, 98, 5, 3914, https://doi.org/10.1063/1.464018 . [all data]

Go To: Top, Vibrational and/or electronic energy levels, References

Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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