C6D

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 19041.26 gas B-X 524 526 Kotterer and Maier, 1997
Kirkwood, Linnartz, et al., 1998
Linnartz, Motylewski, et al., 1999
Zhao, Haddad, et al., 2011
To = 18900 ± 10 Ne Kotterer and Maier, 1997

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 1452 ± 50 gas Taylor, Xu, et al., 1998
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 2 CC stretch 2202 ± 70 gas PE Taylor, Xu, et al., 1998

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ CðC stretch 1862.4 Ar IR Doyle, Shen, et al., 1991

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kotterer and Maier, 1997
Kotterer, M.; Maier, J.P., Electronic spectrum of C6H: in the gas-phase detected by cavity ringdown, Chem. Phys. Lett., 1997, 266, 3-4, 342, https://doi.org/10.1016/S0009-2614(97)00010-9 . [all data]

Kirkwood, Linnartz, et al., 1998
Kirkwood, D.A.; Linnartz, H.; Grutter, M.; Dopfer, O.; Motylewski, T.; Pachkov, M.; Tulej, M.; Wyss, M.; Maier, J.P., Electronic spectroscopy of carbon chains and relevance to astrophysics, Faraday Discuss., 1998, 109, 109, https://doi.org/10.1039/a800072g . [all data]

Linnartz, Motylewski, et al., 1999
Linnartz, H.; Motylewski, T.; Vaizert, O.; Maier, J.P.; Apponi, A.J.; McCarthy, M.C.; Gottlieb, C.A.; Thaddeus, P., Electronic Ground and Excited State Spectroscopy of C6H and C6D, J. Mol. Spectrosc., 1999, 197, 1, 1, https://doi.org/10.1006/jmsp.1999.7885 . [all data]

Zhao, Haddad, et al., 2011
Zhao, D.; Haddad, M.A.; Linnartz, H.; Ubachs, W., C6H and C6D: Electronic spectra and Renner-Teller analysis, J. Chem. Phys., 2011, 135, 4, 044307, https://doi.org/10.1063/1.3609112 . [all data]

Taylor, Xu, et al., 1998
Taylor, T.R.; Xu, C.; Neumark, D.M., Photoelectron spectra of the C[sub 2n]H[sup -] (n=1--4) and C[sub 2n]D[sup -] (n=1--3) anions, J. Chem. Phys., 1998, 108, 24, 10018, https://doi.org/10.1063/1.476462 . [all data]

Doyle, Shen, et al., 1991
Doyle, T.J.; Shen, L.N.; Rittby, C.M.L.; Graham, W.R.M., A C≡C stretching vibration of the C6H (hexatriynyl) radical in Ar at 10 K, J. Chem. Phys., 1991, 95, 9, 6224, https://doi.org/10.1063/1.461568 . [all data]

Notes

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