1,3,5-C6D3F3+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 21923.8 gas B-X 437 544 Bondybey and Miller, 1979
Cossart-Magos, Cossart, et al., 1979
Klapstein, Leutwyler, et al., 1984
To = 21831 Ne B-X 400 458 Bondybey, Miller, et al., 1979
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1' 3 923 gas EM Cossart-Magos, Cossart, et al., 1979
3 932 Ne LF Bondybey, Miller, et al., 1979
4 560 gas LF EM Bondybey and Miller, 1979
Cossart-Magos, Cossart, et al., 1979
4 569 Ne LF Bondybey, Miller, et al., 1979
e' 9 1470 gas LF Bondybey and Miller, 1979
9 1475 Ne LF Bondybey, Miller, et al., 1979
12 777 Ne LF Bondybey, Miller, et al., 1979
13 458 gas LF EM Bondybey and Miller, 1979
Cossart-Magos, Cossart, et al., 1979
13 469 Ne LF Bondybey, Miller, et al., 1979
Bondybey, English, et al., 1983
14 320 Ne LF Bondybey, Miller, et al., 1979
17 198 H Ne LF Bondybey, Miller, et al., 1979

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1' 1 2247 gas EM Cossart-Magos, Cossart, et al., 1979
3 976.1 gas EM EF Cossart-Magos, Cossart, et al., 1979
Klapstein, Leutwyler, et al., 1984
4 586.5 gas EM EF Cossart-Magos, Cossart, et al., 1979
Klapstein, Leutwyler, et al., 1984
4 592 Ne LF Bondybey, Miller, et al., 1979
e' 9 1625 gas EM Cossart-Magos, Cossart, et al., 1979
9 1612 Ne LF Bondybey, Miller, et al., 1979
10 1484 gas EM Cossart-Magos, Cossart, et al., 1979
11 1053.0 gas EF Klapstein, Leutwyler, et al., 1984
12 780 Ne LF Bondybey, Miller, et al., 1979
13 532.3 gas EM EF Cossart-Magos, Cossart, et al., 1979
Klapstein, Leutwyler, et al., 1984
13 541 Ne LF Bondybey, Miller, et al., 1979
Bondybey, English, et al., 1983
14 334 Ne LF Bondybey, Miller, et al., 1979
Bondybey, English, et al., 1983

Notes

H(1/2)(2ν)
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bondybey and Miller, 1979
Bondybey, V.E.; Miller, T.A., Laser induced fluorescence from fluorobenzene radical cations in the gas phase, J. Chem. Phys., 1979, 70, 1, 138, https://doi.org/10.1063/1.437231 . [all data]

Cossart-Magos, Cossart, et al., 1979
Cossart-Magos, C.; Cossart, D.; Leach, S., Jahn---Teller effects in substituted benzene cations. II. Gas phase emission spectrum of 1, 3, 5-C6F3D+3 and comparison with 1, 3, 5-C6F3H+3, Chem. Phys., 1979, 41, 3, 345, https://doi.org/10.1016/0301-0104(79)80039-7 . [all data]

Klapstein, Leutwyler, et al., 1984
Klapstein, D.; Leutwyler, S.; Maier, J.P.; Cossart-Magos, C.; Cossart, D.; Leach, S., The, Mol. Phys., 1984, 51, 2, 413, https://doi.org/10.1080/00268978400100281 . [all data]

Bondybey, Miller, et al., 1979
Bondybey, V.E.; Miller, T.A.; English, J.H., Laser induced fluorescence spectra of symmetrically substituted trihalobenzene radical cations, J. Chem. Phys., 1979, 71, 3, 1088, https://doi.org/10.1063/1.438474 . [all data]

Bondybey, English, et al., 1983
Bondybey, V.E.; English, J.H.; Miller, T.A., Spectroscopic and dynamical studies of vibrationally unrelaxed fluorescence from halobenzene cations in a neon matrix, J. Phys. Chem., 1983, 87, 8, 1300, https://doi.org/10.1021/j100231a007 . [all data]

Notes

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