C6D5CD2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 22455 ± 10 gas Cossart-Magos and Leach, 1976

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 22093.7 gas A-X Grajcar and Leach, 1964
Cossart-Magos and Leach, 1972
To = 21962 Ar A-X 434 502 Miller and Andrews, 1981
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
844 Ar LF Miller and Andrews, 1981
731 Ar LF Miller and Andrews, 1981
6a Ring deform. 404 Ar LF Miller and Andrews, 1981

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 8a Ring stretch 1593 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
19a Ring stretch 1327 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
19a Ring stretch 1323 Ar LF Miller and Andrews, 1981
7a C-CD2 stretch 1204 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
1 Ring breathing 945.7 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
Cossart-Magos and Leach, 1972
1 Ring breathing 945 Ar LF Miller and Andrews, 1981
9a CD deform. 895 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
18a CD deform. 848 gas EM Watmann-Grajcar, 1969
12a Ring stretch 791 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
6a Ring deform. 497.5 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
Cossart-Magos and Leach, 1972
6a Ring deform. 495 Ar LF Miller and Andrews, 1981
a2 10a CD deform. 750 gas EM Watmann-Grajcar, 1969
16a Ring deform. 305 gas EM Watmann-Grajcar, 1969
b1 16b Ring deform. 376 gas EM Watmann-Grajcar, 1969
b2 8b Ring stretch 1495 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
8b Ring stretch 1490 Ar LF Miller and Andrews, 1981
15 CD deform. 848 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
6b Ring deform. 589.1 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
Cossart-Magos and Leach, 1972
6b Ring deform. 588 Ar LF Miller and Andrews, 1981
18b CD deform. 305 gas EM Grajcar and Leach, 1964
Watmann-Grajcar, 1969
18b CD deform. 303 Ar LF Miller and Andrews, 1981

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cossart-Magos and Leach, 1976
Cossart-Magos, C.; Leach, S., Two-mode vibronic interaction between neighboring 1 2A2 and 2 2B2 excited electronic states of the benzyl radical, J. Chem. Phys., 1976, 64, 10, 4006, https://doi.org/10.1063/1.432034 . [all data]

Grajcar and Leach, 1964
Grajcar, L.; Leach, S., J. Chim. Phys., 1964, 61, 1523. [all data]

Cossart-Magos and Leach, 1972
Cossart-Magos, C.; Leach, S., Determination of the Symmetry of the First Excited Electronic State of Benzyl by Rotational Contour Analysis of Vibronic Bands of the Emission Spectra of C6H5CH2, C6H5CD2, and C6D5CD2, J. Chem. Phys., 1972, 56, 4, 1534, https://doi.org/10.1063/1.1677403 . [all data]

Miller and Andrews, 1981
Miller, J.H.; Andrews, L., Emission and excitation spectra of benzyl radicals in solid argon, J. Mol. Spect., 1981, 90, 1, 20, https://doi.org/10.1016/0022-2852(81)90328-3 . [all data]

Watmann-Grajcar, 1969
Watmann-Grajcar, L., J. Chim. Phys., 1969, 66, 1023. [all data]

Notes

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