CD3CCCl+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 28314 ± 3 gas A-X 335 385 Klapstein, Kuhn, et al., 1986
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 3 CD3 deform. 963 ± 3 gas LF Klapstein, Kuhn, et al., 1986
5 CCl stretch 464 ± 3 gas LF EF Klapstein, Kuhn, et al., 1986
e 9 Skel. bend 263 H gas LF Klapstein, Kuhn, et al., 1986
10 CCl bend 155 H gas LF Klapstein, Kuhn, et al., 1986

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 3 CD3 deform. 995 ± 3 gas EF Klapstein, Kuhn, et al., 1986
5 CCl stretch 566 ± 3 gas EF Klapstein, Kuhn, et al., 1986
e 9 Skel. bend 311 T gas EF Klapstein, Kuhn, et al., 1986
10 CCl bend 222 T gas EF Klapstein, Kuhn, et al., 1986

Notes

H(1/2)(2ν)
TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Klapstein, Kuhn, et al., 1986
Klapstein, D.; Kuhn, R.; Maier, J.P.; Ochsner, M.; Wyttenbach, T., Spectroscopic characterization of organic cations: emission and laser-excitation spectra of rotationally cooled CH3«58872»C«58876»C«58872»X+, X «58872» Cl, Br, Chem. Phys., 1986, 101, 1, 133, https://doi.org/10.1016/0301-0104(86)87029-X . [all data]

Notes

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