CaOCD3
- Formula: CD3CaO
- Molecular weight: 74.130
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 17682.30 | gas | B-X | 528 | 600 | Wormsbecher and Suenram, 1982 | ||
Linton, Ross, et al., 2008 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 3 | CO stretch | 1156 ± 5 | gas | LF | Wormsbecher and Suenram, 1982 | |
4 | CaO stretch | 476 ± 5 | gas | LF | Wormsbecher and Suenram, 1982 | ||
e | 8 | CaOC bend | 166 ± 5 | gas | LF | Wormsbecher and Suenram, 1982 | |
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 15915.19 | gas | A-X | 584 | 630 | Wormsbecher and Suenram, 1982 | ||
Crozet, Ross, et al., 2005 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 3 | CO stretch | 1156 ± 5 | gas | LF | Wormsbecher and Suenram, 1982 | |
4 | CaO stretch | 481.62 | gas | LF | Wormsbecher and Suenram, 1982 Crozet, Ross, et al., 2005 | ||
e | 8 | CaOC bend | 140 ± 5 | gas | LF | Wormsbecher and Suenram, 1982 | |
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 4 | CaO stretch | 467 ± 5 | gas | LF | Wormsbecher and Suenram, 1982 | |
e | 8 | CaOC bend | 142 ± 5 | gas | LF | Wormsbecher and Suenram, 1982 | |
Notes
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wormsbecher and Suenram, 1982
Wormsbecher, R.F.; Suenram, R.D.,
Laser spectroscopy and chemiluminescence from the monomethoxides of Ca, Sr, and Ba,
J. Mol. Spectrosc., 1982, 95, 2, 391, https://doi.org/10.1016/0022-2852(82)90138-2
. [all data]
Linton, Ross, et al., 2008
Linton, C.; Ross, A.J.; Adam, A.G.; Crozet, P.; Downie, L.E.; Granger, A.D.; Hopkins, W.S.,
Isotopic study of the transition of calcium monomethoxide using laser excitation and population depletion spectroscopy,
J. Mol. Spectrosc., 2008, 250, 2, 98, https://doi.org/10.1016/j.jms.2008.05.002
. [all data]
Crozet, Ross, et al., 2005
Crozet, P.; Ross, A.J.; Linton, C.; Adam, A.G.; Hopkins, W.S.; Le Roy, R.J.,
Geometry of the CaOCH3 radical from isotope effects in the transition,
J. Mol. Spectrosc., 2005, 229, 2, 224, https://doi.org/10.1016/j.jms.2004.09.006
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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