CD3O-
- Formula: CD3O-
- Molecular weight: 34.0530
- Information on this page:
- Options:
Vibrational and/or electronic energy levels
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td = 12539 ± 15 | gas | Engleking, Ellison, et al., 1978 | |||||
Oakes, Harding, et al., 1985 | |||||||
Osborn, Leahy, et al., 1998 | |||||||
Ramond, Davico, et al., 2000 | |||||||
Nee, Osterwalder, et al., 2006 | |||||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 3 | 839 | gas | TPE | Nee, Osterwalder, et al., 2006 | ||
e | 4 | CD3 stretch | 1710 | gas | TPE | Nee, Osterwalder, et al., 2006 | |
5 | 992 | gas | TPE | Nee, Osterwalder, et al., 2006 | |||
6 | 944 | gas | TPE | Nee, Osterwalder, et al., 2006 | |||
Notes
d | Photodissociation threshold |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Engleking, Ellison, et al., 1978
Engleking, P.C.; Ellison, G.B.; Lineberger, W.C.,
Laser photodetachment electron spectrometry of methoxide, deuteromethoxide, and thiomethoxide: Electron affinities and vibrational structure of CH3O, and CH3S,
J. Chem. Phys., 1978, 69, 1826. [all data]
Oakes, Harding, et al., 1985
Oakes, J.M.; Harding, L.B.; Ellison, G.B.,
The photoelectron spectroscopy of HO2-,
J. Chem. Phys., 1985, 83, 5400. [all data]
Osborn, Leahy, et al., 1998
Osborn, D.L.; Leahy, D.J.; Kim, E.H.; de Beer, E.; Neumark, D.M.,
Photoelectron spectroscopy of CH3O- and CD3O-,
Chem. Phys. Lett., 1998, 292, 4-6, 651, https://doi.org/10.1016/S0009-2614(98)00717-9
. [all data]
Ramond, Davico, et al., 2000
Ramond, T.M.; Davico, G.E.; Schwartz, R.L.; Lineberger, W.C.,
Vibronic structure of alkoxy radicals via photoelectron spectroscopy,
J. Chem. Phys., 2000, 112, 3, 1158, https://doi.org/10.1063/1.480767
. [all data]
Nee, Osterwalder, et al., 2006
Nee, M.J.; Osterwalder, A.; Zhou, J.; Neumark, D.M.,
Slow electron velocity-map imaging photoelectron spectra of the methoxide anion,
J. Chem. Phys., 2006, 125, 1, 014306, https://doi.org/10.1063/1.2212411
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.