CD3I+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16982 gas Goss, McGilvery, et al., 1981
Woodward, Colson, et al., 1986
Weinkauf, Walter, et al., 1987
Walter, Weinkauf, et al., 1988
Lee, Bae, et al., 2008
Bae and Kim, 2008
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CD3 stretch 2100 gas PF Woodward, Colson, et al., 1986
2 Umbrella 918 gas PF Weinkauf, Walter, et al., 1987
Walter, Weinkauf, et al., 1988
3 CI stretch 276.3 gas PF Weinkauf, Walter, et al., 1987
Walter, Weinkauf, et al., 1988

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CD3 stretch 2127 ± 3 gas TPE TPI Walter, Weinkauf, et al., 1988
Strobel, Fischer, et al., 1994
Lee, Bae, et al., 2008
2 CD3 umbrella 949 ± 3 gas TPE TPI Goss, McGilvery, et al., 1981
Strobel, Fischer, et al., 1994
Lee, Bae, et al., 2008
3 CI stretch 456 ± 3 gas TPE TPI Walter, Weinkauf, et al., 1988
Strobel, Fischer, et al., 1994
Lee, Bae, et al., 2008
e 4 CD3 stretch 2289 ± 3 gas TPI Lee, Bae, et al., 2008
5 Deformation 1012 ± 3 gas TPI Lee, Bae, et al., 2008
6 CD3 rock 640 ± 3 gas TPE TPI Strobel, Fischer, et al., 1994
Lee, Bae, et al., 2008

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Goss, McGilvery, et al., 1981
Goss, S.P.; McGilvery, D.C.; Morrison, J.D.; Smith, D.L., The photodissociation of some alkyl iodide cations, J. Chem. Phys., 1981, 75, 4, 1820, https://doi.org/10.1063/1.442261 . [all data]

Woodward, Colson, et al., 1986
Woodward, A.M.; Colson, S.D.; Chupka, W.A.; White, M.G., Vibrational analysis of the ~A-~X photodissociation spectrum of methyl iodide, J. Phys. Chem., 1986, 90, 2, 173, https://doi.org/10.1021/j100274a014 . [all data]

Weinkauf, Walter, et al., 1987
Weinkauf, R.; Walter, K.; Boesl, U.; Schlag, E.W., Mass-selected molecular ion spectra: (1+1)-Photodissociation spectroscopy of CH3I+ and CD3I+, Chem. Phys. Lett., 1987, 141, 4, 267, https://doi.org/10.1016/0009-2614(87)85022-4 . [all data]

Walter, Weinkauf, et al., 1988
Walter, K.; Weinkauf, R.; Boesl, U.; Schlag, E.W., Molecular ion spectroscopy: Mass selected, resonant two-photon dissociation spectra of CH3I+ and CD3I+, J. Chem. Phys., 1988, 89, 4, 1914, https://doi.org/10.1063/1.455088 . [all data]

Lee, Bae, et al., 2008
Lee, M.; Bae, Y.J.; Kim, M.S., K selection in one-photon mass-analyzed threshold ionization of CH[sub 3]I and CD[sub 3]I to the X [sup 2]E[sub 3«8725»2] state cations, J. Chem. Phys., 2008, 128, 4, 044310, https://doi.org/10.1063/1.2823032 . [all data]

Bae and Kim, 2008
Bae, Y.J.; Kim, M.S., Photodissociation Spectroscopy of CD, ChemPhysChem, 2008, 9, 12, 1709, https://doi.org/10.1002/cphc.200800207 . [all data]

Strobel, Fischer, et al., 1994
Strobel, A.; Fischer, I.; Lochschmidt, A.; Muller-Dethlefs, K.; Bondybey, V.E., Photodissociation Dynamics of CH3I and CD3I Probed by Zero Kinetic Energy Photoelectron Spectroscopy, J. Phys. Chem., 1994, 98, 8, 3035, https://doi.org/10.1021/j100059a008 . [all data]

Notes

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