CD3S
- Formula: CD3S
- Molecular weight: 50.118
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| Td = 28089 | gas | Bise, Choi, et al., 1999 | |||||
State: A
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| To = 26574 | gas | A-X | 339 | 378 | Suzuki, Inoue, et al., 1984 | ||
| Bise, Choi, et al., 1999 | |||||||
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a1 | 2 | Umbrella | 837 ± 1 | gas | LF | Suzuki, Inoue, et al., 1984 | |
| 3 | CS stretch | 395 ± 1 | gas | LF | Suzuki, Inoue, et al., 1984 Bise, Choi, et al., 1999 | ||
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a1 | 2 | Umbrella | 1100 ± 50 | gas | PD | Janousek and Brauman, 1980 | |
| 3 | CS stretch | 667 ± 1 | gas | PD LF | Janousek and Brauman, 1980 Suzuki, Inoue, et al., 1984 | ||
| e | 5 | DCS deform. | 780 | gas | PD | Janousek and Brauman, 1980 | |
Notes
| o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
| d | Photodissociation threshold |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bise, Choi, et al., 1999
Bise, R.T.; Choi, H.; Pedersen, H.B.; Mordaunt, D.H.; Neumark, D.M.,
Photodissociation spectroscopy and dynamics of the methylthio radical (CH[sub 3]S),
J. Chem. Phys., 1999, 110, 2, 805, https://doi.org/10.1063/1.478048
. [all data]
Suzuki, Inoue, et al., 1984
Suzuki, M.; Inoue, G.; Akimoto, H.,
Laser induced fluorescence of CH3S and CD3S radicals,
J. Chem. Phys., 1984, 81, 12, 5405, https://doi.org/10.1063/1.447685
. [all data]
Janousek and Brauman, 1980
Janousek, B.K.; Brauman, J.I.,
Electron photodetachment of thiomethoxyl and deuterothiomethoxyl anions: Electron affinities, vibrational frequencies, and spin-orbit splitting in CH3S- and CD3S-,
J. Chem. Phys., 1980, 72, 694. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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