CD3N


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 31774.158 ± 0.002 gas A-X 294 365 Franken, Perner, et al., 1970
Carrick and Engelking, 1984
Carrick, Brazier, et al., 1987
Chappell and Engelking, 1988
To = 31516 ± 30 N2 A-X 277 318 Ferrante, 1987
Ferrante, 1991


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 CD3 deform. 1044 T N2 AB Ferrante, 1991
CN stretch 759 ± 4 gas UV Franken, Perner, et al., 1970
Carrick and Engelking, 1984
CN stretch 695 T N2 AB Ferrante, 1991
e CD3 rock 579 ± 4 gas EM Carrick and Engelking, 1984

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 CD3 deform. 941 ± 4 gas EM Chappell and Engelking, 1988
3 CN stretch 1110 ± 4 gas EM Carrick and Engelking, 1984
Chappell and Engelking, 1988
e 6 CD3 rock 748 ± 8 gas EM Carrick and Engelking, 1984
Chappell and Engelking, 1988

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Franken, Perner, et al., 1970
Franken, Th.; Perner, D.; Bosnali, M.W., Z. Naturforsch., 1970, 25a, 151. [all data]

Carrick and Engelking, 1984
Carrick, P.G.; Engelking, P.C., The electronic emission spectrum of methylnitrene, J. Chem. Phys., 1984, 81, 4, 1661, https://doi.org/10.1063/1.447891 . [all data]

Carrick, Brazier, et al., 1987
Carrick, P.G.; Brazier, C.R.; Bernath, P.F.; Engelking, P.C., The structure of the methylnitrene radical, J. Am. Chem. Soc., 1987, 109, 17, 5100, https://doi.org/10.1021/ja00251a008 . [all data]

Chappell and Engelking, 1988
Chappell, E.L.; Engelking, P.C., Methylnitrene free radical. Ground state vibrational fundamentals and harmonic force field from jet-cooled emission spectra of the A 3E--X 3A2 band system, J. Chem. Phys., 1988, 89, 10, 6007, https://doi.org/10.1063/1.455415 . [all data]

Ferrante, 1987
Ferrante, R.F., Spectroscopy of matrix-isolated methylnitrene, J. Chem. Phys., 1987, 86, 1, 25, https://doi.org/10.1063/1.452775 . [all data]

Ferrante, 1991
Ferrante, R.F., Vibrational frequencies in the A 3E state of methylnitrene, J. Chem. Phys., 1991, 94, 6, 4678, https://doi.org/10.1063/1.460600 . [all data]


Notes

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