ND4


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   3p 2F2


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 14828.285 ± 0.004 gas 3p2F2-3s2A1 675 675 Schuler, Michel, et al., 1955
Herzberg, 1981
Whittaker, Sullivan, et al., 1984
Herzberg, 1984
Alberti, Huber, et al., 1984

State:   3s


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 ND stretch 1960 T gas EM Schuler, Michel, et al., 1955
Herzberg, 1984
e 2 Deformation 1080.25 ± 0.07 gas EM Watson, 1986

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schuler, Michel, et al., 1955
Schuler, H.; Michel, A.; Grun, A.E., Z. Naturforsch. A, 1955, 10, 1. [all data]

Herzberg, 1981
Herzberg, G., Rydberg spectra of triatomic hydrogen and of the ammonium radical, Disc. Faraday Soc., 1981, 71, 165, https://doi.org/10.1039/dc9817100165 . [all data]

Whittaker, Sullivan, et al., 1984
Whittaker, E.A.; Sullivan, B.J.; Bjorklund, G.C.; Wendt, H.R.; Hunziker, H.E., ND4 Schuler band absorption observed by laser FM spectroscopy in a photochemical reaction, J. Chem. Phys., 1984, 80, 2, 961, https://doi.org/10.1063/1.446757 . [all data]

Herzberg, 1984
Herzberg, G., Spectra of the ammonium radical: the schüler bands, J. Astrophys. Astron., 1984, 5, 2, 131, https://doi.org/10.1007/BF02714985 . [all data]

Alberti, Huber, et al., 1984
Alberti, F.; Huber, K.P.; Watson, J.K.G., Absorption spectrum and analysis of the ND4 Schüler band, J. Mol. Spectrosc., 1984, 107, 1, 133, https://doi.org/10.1016/0022-2852(84)90272-8 . [all data]

Watson, 1986
Watson, J.K.G., Proc. l7th International Symposium on Free Radicals, 1986, Nat. Bur. Stand. (U. S.) Spec. Publ. 716, K. M. Evenson, Ed., pp. 650-670. [all data]


Notes

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