DCO2-
- Formula: CDO2-
- Molecular weight: 46.0242
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Td = 28371 ± 8 | gas | Kim, Bradforth, et al., 1995 | |||||
Forney, Jacox, et al., 2003 | |||||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | CD stretch | 1842 | A | gas | PF | Gerardi, DeBlase, et al., 2011 |
1 | CD stretch | 1844.6 | Ne | IR | Forney, Jacox, et al., 2003 Jacox and Thompson, 2003 | ||
2 | CO2 s-stretch | 1305 ± 8 | gas | PE | Garand, Klein, et al., 2010 | ||
2 | CO2 s-stretch | 1297 | A | gas | PF | Gerardi, DeBlase, et al., 2011 | |
2 | CO2 s-stretch | 1309.1 | Ne | IR | Forney, Jacox, et al., 2003 | ||
3 | CO2 bend | 732 ± 8 | gas | PE | Kim, Bradforth, et al., 1995 Garand, Klein, et al., 2010 | ||
3 | CO2 bend | 736.9 | Ne | IR | Forney, Jacox, et al., 2003 | ||
b2 | 5 | CO2 a-stretch | 1622 | A | gas | PF | Gerardi, DeBlase, et al., 2011 |
5 | CO2 a-stretch | 1625.0 | Ne | IR | Forney, Jacox, et al., 2003 | ||
5 | CO2 a-stretch | 1622.5 | Ne | IR | Forney, Jacox, et al., 2003 | ||
Notes
d | Photodissociation threshold |
A | 0~1 cm-1 uncertainty |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kim, Bradforth, et al., 1995
Kim, E.H.; Bradforth, S.E.; Arnold, D.W.; Metz, R.B.; Neumark, D.M.,
Study of HCO2 and DCO2 by Negative Ion Photoelectron Spectroscopy,
J. Chem. Phys., 1995, 103, 18, 7801, https://doi.org/10.1063/1.470196
. [all data]
Forney, Jacox, et al., 2003
Forney, D.; Jacox, M.E.; Thompson, W.E.,
Infrared spectra of trans-HOCO, HCOOH[sup +], and HCO[sub 2][sup -] trapped in solid neon,
J. Chem. Phys., 2003, 119, 20, 10814, https://doi.org/10.1063/1.1621382
. [all data]
Gerardi, DeBlase, et al., 2011
Gerardi, H.K.; DeBlase, A.F.; Su, X.; Jordan, K.D.; McCoy, A.B.; Johnson, M.A.,
Unraveling the Anomalous Solvatochromic Response of the Formate Ion Vibrational Spectrum: An Infrared, Ar-Tagging Study of the HCO,
J. Phys. Chem. Lett., 2011, 2, 19, 2437, https://doi.org/10.1021/jz200937v
. [all data]
Jacox and Thompson, 2003
Jacox, M.E.; Thompson, W.E.,
Infrared spectra of HOCO[sup +] and of the complex of H[sub 2] with CO[sub 2][sup -] trapped in solid neon,
J. Chem. Phys., 2003, 119, 20, 10824, https://doi.org/10.1063/1.1621383
. [all data]
Garand, Klein, et al., 2010
Garand, E.; Klein, K.; Stanton, J.F.; Zhou, J.; Yacovitch, T.I.; Neumark, D.M.,
Vibronic Structure of the Formyloxyl Radical (HCO,
J. Phys. Chem. A, 2010, 114, 3, 1374, https://doi.org/10.1021/jp9067894
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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