DCO2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 4110 gas Kim, Bradforth, et al., 1995
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 3 CO2 bend 700 ± 50 gas PE Kim, Bradforth, et al., 1995

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 87 ± 8 gas Kim, Bradforth, et al., 1995
Garand, Klein, et al., 2010
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 3 CO2 bend 579 ± 8 gas PE Garand, Klein, et al., 2010

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 2 CO2 s-stretch 1136 ± 8 gas PE Garand, Klein, et al., 2010
3 CO2 bend 563 ± 8 gas PE Garand, Klein, et al., 2010
b2 6 Deformation 430 ± 8 gas PE Garand, Klein, et al., 2010

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kim, Bradforth, et al., 1995
Kim, E.H.; Bradforth, S.E.; Arnold, D.W.; Metz, R.B.; Neumark, D.M., Study of HCO2 and DCO2 by Negative Ion Photoelectron Spectroscopy, J. Chem. Phys., 1995, 103, 18, 7801, https://doi.org/10.1063/1.470196 . [all data]

Garand, Klein, et al., 2010
Garand, E.; Klein, K.; Stanton, J.F.; Zhou, J.; Yacovitch, T.I.; Neumark, D.M., Vibronic Structure of the Formyloxyl Radical (HCO, J. Phys. Chem. A, 2010, 114, 3, 1374, https://doi.org/10.1021/jp9067894 . [all data]

Notes

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