DCOCl
- Formula: CDClO
- Molecular weight: 65.477
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| To = 32775.3 | gas | A-X | 283 | 313 | Judge and Moule, 1985 | ||
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a' | 2 | CO stretch | 1092.0 | gas | AB | Judge and Moule, 1985 | |
| 4 | CCl stretch | 633.4 | gas | AB | Judge and Moule, 1985 | ||
| 5 | ClCO deform. | 303.1 | gas | AB | Judge and Moule, 1985 | ||
| a | 6 | Umbrella (OPLA) | 566.5 | gas | AB | Judge and Moule, 1985 | |
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a' | 1 | CD stretch | 2204.3 | gas | IR | Davis and Gerry, 1983 Joo, Laboy, et al., 1995 | |
| 2 | CO stretch | 1749.1 | gas | IR | Davis and Gerry, 1983 Joo, Laboy, et al., 1995 | ||
| 3 | CD bend | 986.11 | gas | IR | Davis and Gerry, 1983 Joo, Laboy, et al., 1995 | ||
| 4 | CCl stretch | 700.77 | gas | IR | Davis and Gerry, 1983 Joo, Laboy, et al., 1995 Joo, Clouthier, et al., 1995 | ||
| 5 | CCl bend | 455.78 | gas | IR | Joo, Laboy, et al., 1995 | ||
| a | 6 | OPLA | 781.50 | gas | IR | Joo, Laboy, et al., 1995 Joo, Clouthier, et al., 1995 | |
Notes
| o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Judge and Moule, 1985
Judge, R.H.; Moule, D.C.,
The electronic transition in formyl chloride, CHClO,
J. Mol. Spectrosc., 1985, 113, 2, 302, https://doi.org/10.1016/0022-2852(85)90269-3
. [all data]
Davis and Gerry, 1983
Davis, R.W.; Gerry, M.C.L.,
The microwave spectrum, harmonic force field, and structure of formyl chloride,
J. Mol. Spectrosc., 1983, 97, 1, 117, https://doi.org/10.1016/0022-2852(83)90340-5
. [all data]
Joo, Laboy, et al., 1995
Joo, D.-L.; Laboy, J.; Kolomeisky, A.; Zhuo, Q.; Clouthier, D.J.; Chan, C.P.; Merer, A.J.; Judge, R.H.,
A High-Resolution Fourier Transform Infrared Study of the ν3, ν4, and ν5 Bands of Deuterated Formyl Chloride (DCOCl),
J. Mol. Spectrosc., 1995, 170, 2, 346, https://doi.org/10.1006/jmsp.1995.1076
. [all data]
Joo, Clouthier, et al., 1995
Joo, D.-L.; Clouthier, D.J.; Merer, A.J.,
A High-Resolution Fourier Transform Infrared Study of the Out-of-Plane Bending Fundamentals of HCOCl and DCOCl,
J. Mol. Spectrosc., 1995, 174, 2, 353, https://doi.org/10.1006/jmsp.1995.0007
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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