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t-DONO


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 26050 ± 10 gas A-X 315 385 Tarte, 1950
Porter, 1951
King and Moule, 1962


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' NO stretch 1147 ± 20 gas AB King and Moule, 1962

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 OD stretch 2651.13 gas IR Jones, Badger, et al., 1951
D'Or and Tarte, 1951
McGraw, Bernitt, et al., 1966
Deeley and Mills, 1983
Dehayem-Kamadjeu, Orphal, et al., 2006
1 OD stretch 2620 N2 IR Hall and Pimentel, 1963
2 N=O stretch 1693.98 gas IR Jones, Badger, et al., 1951
D'Or and Tarte, 1951
McGraw, Bernitt, et al., 1966
Deeley and Mills, 1983
2 N=O stretch 1682 N2 IR Hall and Pimentel, 1963
3 DON bend 1012.68 gas IR Jones, Badger, et al., 1951
D'Or and Tarte, 1951
McGraw, Bernitt, et al., 1966
Deeley and Mills, 1983
3 DON bend 1030 N2 IR Hall and Pimentel, 1963
4 O-N stretch 736.27 gas IR Jones, Badger, et al., 1951
D'Or and Tarte, 1951
McGraw, Bernitt, et al., 1966
Deeley and Mills, 1983
4 O-N stretch 769 N2 IR Hall and Pimentel, 1963
5 ONO bend 590.4 gas IR Jones, Badger, et al., 1951
D'Or and Tarte, 1951
McGraw, Bernitt, et al., 1966
Deeley and Mills, 1983
5 ONO bend 618 N2 IR Hall and Pimentel, 1963
a 6 Torsion 416.1 gas IR Jones, Badger, et al., 1951
McGraw, Bernitt, et al., 1966
Deeley and Mills, 1983
6 Torsion 444 N2 IR Hall and Pimentel, 1963

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Tarte, 1950
Tarte, P., Bull. Soc. Chim. Belges, 1950, 59, 365. [all data]

Porter, 1951
Porter, G., Isotope Effect in the Band Spectrum of HNO2, J. Chem. Phys., 1951, 19, 10, 1278, https://doi.org/10.1063/1.1748012 . [all data]

King and Moule, 1962
King, G.W.; Moule, D., THE ULTRAVIOLET ABSORPTION SPECTRUM OF NITROUS ACID IN THE VAPOR STATE, Can. J. Chem., 1962, 40, 11, 2057, https://doi.org/10.1139/v62-316 . [all data]

Jones, Badger, et al., 1951
Jones, L.H.; Badger, R.M.; Moore, G.E., The Infrared Spectrum and the Structure of Gaseous Nitrous Acid, J. Chem. Phys., 1951, 19, 12, 1599, https://doi.org/10.1063/1.1748129 . [all data]

D'Or and Tarte, 1951
D'Or, L.; Tarte, P., Bull. Soc. Roy. Sci. Liege, 1951, 20, 478. [all data]

McGraw, Bernitt, et al., 1966
McGraw, G.E.; Bernitt, D.L.; Hisatsune, I.C., Infrared Spectra of Isotopic Nitrous Acids, J. Chem. Phys., 1966, 45, 5, 1392, https://doi.org/10.1063/1.1727772 . [all data]

Deeley and Mills, 1983
Deeley, C.M.; Mills, I.M., The infrared vibration---rotation spectrum of trans and cis nitrous acid, J. Mol. Struct., 1983, 100, 199, https://doi.org/10.1016/0022-2860(83)90092-3 . [all data]

Dehayem-Kamadjeu, Orphal, et al., 2006
Dehayem-Kamadjeu, A.; Orphal, J.; Ibrahim, N.; Kleiner, I.; Bouba, O.; Flaud, J.-M., The «upsilon»1 fundamental bands of trans- and cis-DONO studied by high-resolution Fourier-transform spectroscopy, J. Mol. Spectrosc., 2006, 238, 1, 29, https://doi.org/10.1016/j.jms.2006.04.005 . [all data]

Hall and Pimentel, 1963
Hall, R.T.; Pimentel, G.C., Isomerization of Nitrous Acid: An Infrared Photochemical Reaction, J. Chem. Phys., 1963, 38, 8, 1889, https://doi.org/10.1063/1.1733892 . [all data]


Notes

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