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DCCCl+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 26997.5 gas A-X 328 488 Klapstein, Kuhn, et al., 1984
Klapstein, Kuhn, et al., 1985
King, Maier, et al., 1985


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 CD stretch 2561.5 ± 0.2 gas LF King, Maier, et al., 1985
2 CC stretch 1919.7 ± 0.2 gas LF King, Maier, et al., 1985
3 CCl stretch 587.2 ± 0.3 gas EF LF Klapstein, Kuhn, et al., 1984
Klapstein, Kuhn, et al., 1985
King, Maier, et al., 1985
Pi 5 CCCl bend 216 gas EF Klapstein, Kuhn, et al., 1984

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 CD stretch 2475 T gas EF Klapstein, Kuhn, et al., 1984
2 CC stretch 1882.0 ± 0.3 gas EF Klapstein, Kuhn, et al., 1984
Klapstein, Kuhn, et al., 1985
3 CCl stretch 817.0 ± 0.3 gas EF Klapstein, Kuhn, et al., 1984
Klapstein, Kuhn, et al., 1985
Pi 4 DCC bend 476 gas EF Klapstein, Kuhn, et al., 1984

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Klapstein, Kuhn, et al., 1984
Klapstein, D.; Kuhn, R.; Maier, J.P., Emission spectra of supersonically cooled chloroacetylene cations, Chem. Phys., 1984, 86, 3, 285, https://doi.org/10.1016/0301-0104(84)80016-6 . [all data]

Klapstein, Kuhn, et al., 1985
Klapstein, D.; Kuhn, R.; Maier, J.P., Vibrational frequencies of isotopic species of X-C«58876»C-H+ and X-C«58876»C-X+, X«58875»Cl, Br in the ~= X«OMEGA» and ~= A«OMEGA» «OMEGA» = , cationic states, J. Electron Spectrosc. Relat. Phenom., 1985, 35, 1, 171, https://doi.org/10.1016/0368-2048(85)80051-7 . [all data]

King, Maier, et al., 1985
King, M.A.; Maier, J.P.; Ochsner, M., Laser-excitation spectra of the chloroacetylene and deuterochloroacetylene cations, ClCCH+ and ClCCD+, J. Chem. Phys., 1985, 83, 7, 3181, https://doi.org/10.1063/1.449175 . [all data]


Notes

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