DCCCl+
- Formula: C2DCl+
- Molecular weight: 61.488
- Information on this page:
- Options:
Vibrational and/or electronic energy levels
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 26997.5 | gas | A-X | 328 | 488 | Klapstein, Kuhn, et al., 1984 | ||
Klapstein, Kuhn, et al., 1985 | |||||||
King, Maier, et al., 1985 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σ+ | 1 | CD stretch | 2561.5 ± 0.2 | gas | LF | King, Maier, et al., 1985 | |
2 | CC stretch | 1919.7 ± 0.2 | gas | LF | King, Maier, et al., 1985 | ||
3 | CCl stretch | 587.2 ± 0.3 | gas | EF LF | Klapstein, Kuhn, et al., 1984 Klapstein, Kuhn, et al., 1985 King, Maier, et al., 1985 | ||
Π | 5 | CCCl bend | 216 | gas | EF | Klapstein, Kuhn, et al., 1984 | |
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Σ+ | 1 | CD stretch | 2475 | T | gas | EF | Klapstein, Kuhn, et al., 1984 |
2 | CC stretch | 1882.0 ± 0.3 | gas | EF | Klapstein, Kuhn, et al., 1984 Klapstein, Kuhn, et al., 1985 | ||
3 | CCl stretch | 817.0 ± 0.3 | gas | EF | Klapstein, Kuhn, et al., 1984 Klapstein, Kuhn, et al., 1985 | ||
Π | 4 | DCC bend | 476 | gas | EF | Klapstein, Kuhn, et al., 1984 | |
Notes
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Klapstein, Kuhn, et al., 1984
Klapstein, D.; Kuhn, R.; Maier, J.P.,
Emission spectra of supersonically cooled chloroacetylene cations,
Chem. Phys., 1984, 86, 3, 285, https://doi.org/10.1016/0301-0104(84)80016-6
. [all data]
Klapstein, Kuhn, et al., 1985
Klapstein, D.; Kuhn, R.; Maier, J.P.,
Vibrational frequencies of isotopic species of X-C«58876»C-H+ and X-C«58876»C-X+, X«58875»Cl, Br in the ≈ XΩ and ≈ AΩ Ω = , cationic states,
J. Electron Spectrosc. Relat. Phenom., 1985, 35, 1, 171, https://doi.org/10.1016/0368-2048(85)80051-7
. [all data]
King, Maier, et al., 1985
King, M.A.; Maier, J.P.; Ochsner, M.,
Laser-excitation spectra of the chloroacetylene and deuterochloroacetylene cations, ClCCH+ and ClCCD+,
J. Chem. Phys., 1985, 83, 7, 3181, https://doi.org/10.1063/1.449175
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.