D2CS
- Formula: CD2S
- Molecular weight: 48.104
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 47325.563 ± 0.004 | gas | C-X | 211 | 212 | Judge, Drury-Lessard, et al., 1978 | ||
Drury and Moule, 1982 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | CD stretch | 1783 | gas | AB | Judge, Drury-Lessard, et al., 1978 Drury and Moule, 1982 | |
2 | CD2 scissors | 746 | gas | AB | Drury and Moule, 1982 | ||
State: B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 45200 | T | gas | B-X | 185 | 215 | Drury, Lai, et al., 1982 | |
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 3 | CS stretch | 467 | gas | AB | Drury, Lai, et al., 1982 | |
b1 | 4 | OPLA | 263 | H | gas | AB | Drury, Lai, et al., 1982 |
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 16483.502 ± 0.008 | gas | A-X | 440 | 610 | Judge and King, 1975 | ||
Judge and King, 1979 | |||||||
Judge and King, 1979, 2 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | CD stretch | 2139 ± 2 | gas | AB | Judge and King, 1979 | |
2 | CD2 scissors | 1013 ± 2 | gas | AB | Judge and King, 1979 | ||
3 | CS stretch | 771.3 ± 0.5 | gas | AB | Judge and King, 1975 Judge and King, 1979 | ||
b1 | 4 | OPLA | 275.33 | gas | AB | Judge and King, 1979 | |
b2 | 5 | CD stretch | 2324.85 | gas | AB | Judge and King, 1979 | |
6 | CD2 rock | 599 ± 2 | gas | AB | Judge and King, 1979 | ||
State: a
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 14613.54 | gas | a-X | 610 | 815 | Judge and King, 1975 | ||
Judge, Moule, et al., 1980 | |||||||
Glinski, Getty, et al., 1985 | |||||||
Glinski, Taylor, et al., 1991 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 2 | CD2 scissors | 1012 | gas | AB CL | Judge, Moule, et al., 1980 Glinski, Taylor, et al., 1991 | |
3 | CS stretch | 798 | gas | AB CL | Judge and King, 1975 Judge, Moule, et al., 1980 Glinski, Taylor, et al., 1991 | ||
b1 | 4 | OPLA | 219.4 ± 5.0 | gas | AB CL | Jensen and Bunker, 1982 Glinski, Getty, et al., 1985 Glinski, Taylor, et al., 1991 | |
b2 | 6 | CD2 rock | 572.6 ± 5.0 | gas | CL | Glinski, Taylor, et al., 1991 | |
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | CD stretch | 2158.5 | gas | IR | Turner, Halonen, et al., 1981 | |
1 | CD stretch | 2155 | m | Ar | IR | Torres, Safarik, et al., 1982 | |
2 | CD2 scissors | 1171.8 | gas | IR | Turner, Halonen, et al., 1981 | ||
2 | CD2 scissors | 1167 | m | N2 | IR | Torres, Safarik, et al., 1982 | |
3 | CS stretch | 936.13 | gas | IR LS | Turner, Halonen, et al., 1981 Duxbury, Kato, et al., 1981 | ||
3 | CS stretch | 941 | w | Ar | IR | Jacox and Milligan, 1975 Torres, Safarik, et al., 1982 | |
3 | CS stretch | 939 | w m | N2 | IR | Jacox and Milligan, 1975 | |
b1 | 4 | OPLA | 781.2 | gas | IR | Turner, Halonen, et al., 1981 | |
4 | OPLA | 783 | m | Ar | IR | Jacox and Milligan, 1975 Torres, Safarik, et al., 1982 | |
4 | OPLA | 784 | s | N2 | IR | Jacox and Milligan, 1975 | |
b2 | 6 | CD2 rock | 757.4 | gas | IR | Turner, Halonen, et al., 1981 | |
Notes
w | Weak |
m | Medium |
s | Strong |
H | (1/2)(2ν) |
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Judge, Drury-Lessard, et al., 1978
Judge, R.H.; Drury-Lessard, C.R.; Moule, D.C.,
The far ultraviolet spectrum of thioformaldehyde,
Chem. Phys. Lett., 1978, 53, 1, 82, https://doi.org/10.1016/0009-2614(78)80395-9
. [all data]
Drury and Moule, 1982
Drury, C.R.; Moule, D.C.,
The ultraviolet absorption spectrum of thioformaldehyde,
J. Mol. Spectrosc., 1982, 92, 2, 469, https://doi.org/10.1016/0022-2852(82)90116-3
. [all data]
Drury, Lai, et al., 1982
Drury, C.R.; Lai, J.Y.K.; Moule, D.C.,
The B1A2 ← X1A1 absorption spectrum of thioformaldehyde,
Chem. Phys. Lett., 1982, 87, 6, 520, https://doi.org/10.1016/0009-2614(82)83169-2
. [all data]
Judge and King, 1975
Judge, R.H.; King, G.W.,
The Electronic Absorption Spectrum of Thioformaldehyde,
Can. J. Phys., 1975, 53, 19, 1927, https://doi.org/10.1139/p75-241
. [all data]
Judge and King, 1979
Judge, R.H.; King, G.W.,
Thioformaldehyde,
J. Mol. Spectrosc., 1979, 74, 2, 175, https://doi.org/10.1016/0022-2852(79)90048-1
. [all data]
Judge and King, 1979, 2
Judge, R.H.; King, G.W.,
Thioformaldehyde,
J. Mol. Spectrosc., 1979, 78, 1, 51, https://doi.org/10.1016/0022-2852(79)90035-3
. [all data]
Judge, Moule, et al., 1980
Judge, R.H.; Moule, D.C.; King, G.W.,
The absorption spectrum of thioformaldehyde,
J. Mol. Spectrosc., 1980, 81, 1, 37, https://doi.org/10.1016/0022-2852(80)90328-8
. [all data]
Glinski, Getty, et al., 1985
Glinski, R.J.; Getty, J.N.; Birks, J.W.,
Phosphorescence spectra of thioformaldehyde and thioformaldehyde-d2 by chemiluminescence: Identification of the 411 band,
Chem. Phys. Lett., 1985, 117, 4, 359, https://doi.org/10.1016/0009-2614(85)85244-1
. [all data]
Glinski, Taylor, et al., 1991
Glinski, R.J.; Taylor, C.D.; Martin, H.R.,
Chemiluminescence spectra of thioformaldehyde and selenoformaldehyde,
J. Phys. Chem., 1991, 95, 16, 6159, https://doi.org/10.1021/j100169a021
. [all data]
Jensen and Bunker, 1982
Jensen, P.; Bunker, P.R.,
The geometry and the out-of-plane bending potential function of thioformaldehyde in the and electronic states,
J. Mol. Spectrosc., 1982, 95, 1, 92, https://doi.org/10.1016/0022-2852(82)90241-7
. [all data]
Turner, Halonen, et al., 1981
Turner, P.H.; Halonen, L.; Mills, I.M.,
Fourier transform infrared spectra of H2CS and D2CS,
J. Mol. Spectrosc., 1981, 88, 2, 402, https://doi.org/10.1016/0022-2852(81)90190-9
. [all data]
Torres, Safarik, et al., 1982
Torres, M.; Safarik, I.; Clement, A.; Strausz, O.P.,
The generation and vibrational spectrum of matrix isolated thioformaldehyde and dideuterothioformaldehyde,
Can. J. Chem., 1982, 60, 10, 1187, https://doi.org/10.1139/v82-176
. [all data]
Duxbury, Kato, et al., 1981
Duxbury, G.; Kato, H.; Le Lerre, M.L.,
Laser Stark and interferometric studies of thioformaldehyde and methyleneimine,
Discuss. Faraday Soc., 1981, 71, 97, https://doi.org/10.1039/dc9817100097
. [all data]
Jacox and Milligan, 1975
Jacox, M.E.; Milligan, D.E.,
Matrix isolation study of the infrared spectrum of thioformaldehyde,
J. Mol. Spectrosc., 1975, 58, 1, 142, https://doi.org/10.1016/0022-2852(75)90162-9
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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