DNO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 48400 gas 196 206 Callear and Wood, 1971

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 17010 ± 10 gas Dixon and Rosser, 1984
Petersen, 1985

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 13180.3 gas A-X 550 770 Dalby, 1958
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 ND stretch 2176.49 gas AB Bancroft, Hollas, et al., 1962
2 Bend 755.31 gas AB Dalby, 1958
3 NO stretch 1401.28 gas AB Dalby, 1958

State:   a
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 6330 ± 160 gas Ellis and Ellison, 1983
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 2 Bend 750 ± 140 gas PE Ellis and Ellison, 1983
3 NO stretch 1452 ± 140 gas PE Ellis and Ellison, 1983

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 ND stretch 2025.14 gas LS IR Johns and McKellar, 1977
Johns, McKellar, et al., 1983
1 ND stretch 2043 w m Ar IR Jacox and Milligan, 1973
1 ND stretch 2074 m N2 IR Jacox and Milligan, 1973
2 Bend 1153 s Ar IR Jacox and Milligan, 1973
2 Bend 1158.5 m N2 IR Jacox and Milligan, 1973
3 NO stretch 1546.88 gas LS Johns and McKellar, 1977
3 NO stretch 1547 vs Ar IR Jacox and Milligan, 1973
3 NO stretch 1548 vs N2 IR Jacox and Milligan, 1973

Notes

wWeak
mMedium
sStrong
vsVery strong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Callear and Wood, 1971
Callear, A.B.; Wood, P.M., A system of HNO in the far ultra-violet and measurement of its oscillator strength, Trans. Faraday Soc., 1971, 67, 3399, https://doi.org/10.1039/tf9716703399 . [all data]

Dixon and Rosser, 1984
Dixon, R.N.; Rosser, C.A., Predissociation of the DNO molecule and the bond dissociation energy for DNO → D + NO, Chem. Phys. Lett., 1984, 108, 4, 323, https://doi.org/10.1016/0009-2614(84)85199-4 . [all data]

Petersen, 1985
Petersen, J.C., Doppler-limited dye laser excitation spectroscopy of DNO: Predissociation of DNO, J. Mol. Spectrosc., 1985, 110, 2, 277, https://doi.org/10.1016/0022-2852(85)90295-4 . [all data]

Dalby, 1958
Dalby, F.W., THE SPECTRUM AND STRUCTURE OF THE HNO MOLECULE, Can. J. Phys., 1958, 36, 10, 1336, https://doi.org/10.1139/p58-138 . [all data]

Bancroft, Hollas, et al., 1962
Bancroft, J.L.; Hollas, J.M.; Ramsay, D.A., THE ABSORPTION SPECTRA OF HNO AND DNO, Can. J. Phys., 1962, 40, 3, 322, https://doi.org/10.1139/p62-032 . [all data]

Ellis and Ellison, 1983
Ellis, H.B., Jr.; Ellison, G.B., Photoelectron spectroscopy of HNO- and DNO-, J. Chem. Phys., 1983, 78, 6541. [all data]

Johns and McKellar, 1977
Johns, J.W.C.; McKellar, A.R.W., Laser Stark spectroscopy of the fundamental bands of HNO (ν2 and ν3) and DNO (ν1 and ν2), J. Chem. Phys., 1977, 66, 3, 1217, https://doi.org/10.1063/1.434013 . [all data]

Johns, McKellar, et al., 1983
Johns, J.W.C.; McKellar, A.R.W.; Weinberger, E., The infrared spectrum of HNO, Can. J. Phys., 1983, 61, 7, 1106, https://doi.org/10.1139/p83-142 . [all data]

Jacox and Milligan, 1973
Jacox, M.E.; Milligan, D.E., Matrix-isolation study of the reaction of H atoms with NO, J. Mol. Spectrosc., 1973, 48, 3, 536, https://doi.org/10.1016/0022-2852(73)90116-1 . [all data]

Notes

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