DGeCl
- Formula: ClDGe
- Molecular weight: 110.11
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 21614.48 | gas | A-X | 441 | 462 | Harper and Clouthier, 1998 | ||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | GeD stretch | 979.6 ± 0.2 | gas | LF | Harper and Clouthier, 1998 | |
2 | Bend | 321.7 ± 0.2 | gas | LF | Harper and Clouthier, 1998 | ||
3 | GeCl stretch | 398.9 ± 0.2 | gas | LF | Harper and Clouthier, 1998 | ||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | GeD stretch | 1320 ± 2 | gas | LF | Tackett, Clouthier, et al., 2006 | |
1 | GeD stretch | 1343 | w | Ar | IR | Isabel and Guillory, 1971 | |
2 | Bend | 521 ± 2 | gas | LF | Tackett, Clouthier, et al., 2006 | ||
3 | GeCl stretch | 398 ± 2 | gas | LF | Tackett, Clouthier, et al., 2006 | ||
Notes
w | Weak |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Harper and Clouthier, 1998
Harper, W.W.; Clouthier, D.J.,
The electronic spectra of jet-cooled HGeCl and HGeBr,
J. Chem. Phys., 1998, 108, 2, 416, https://doi.org/10.1063/1.475403
. [all data]
Tackett, Clouthier, et al., 2006
Tackett, B.S.; Clouthier, D.J.; Pacheco, K.L.; Schick, G.A.,
The ground state energy levels and molecular structure of jet-cooled HGeCl and DGeCl from single vibronic level emission spectroscopy,
J. Chem. Phys., 2006, 124, 12, 124320, https://doi.org/10.1063/1.2181142
. [all data]
Isabel and Guillory, 1971
Isabel, R.J.; Guillory, W.A.,
Vacuum-Ultraviolet Photolysis of GeH3Cl; the Infrared Spectrum of Matrix-Isolated GeH2Cl,
J. Chem. Phys., 1971, 55, 3, 1197, https://doi.org/10.1063/1.1676205
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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