BaOD

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 13177.318 ± 0.003 gas B-X 730 759 Kinsey-Nielsen, Brazier, et al., 1986

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 11733.58 gas A-X 828 878 Fernando, Douay, et al., 1990
Tandy, Wang, et al., 2009
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 268 gas LF Fernando, Douay, et al., 1990
Σ+ 3 BaO stretch 451 gas LF Fernando, Douay, et al., 1990

State:   A'
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
11283.20 U gas A'-X 886 889 Fernando, Douay, et al., 1990
Tandy, Wang, et al., 2011
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 258 gas LF Fernando, Douay, et al., 1990
Σ+ 3 BaO stretch 469 gas LF Fernando, Douay, et al., 1990

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Π 2 Bend 257.6 ± 0.4 gas LF Kinsey-Nielsen, Brazier, et al., 1986
Σ+ 3 BaO stretch 482.4 ± 0.2 gas LF Kinsey-Nielsen, Brazier, et al., 1986
3 BaO stretch 413.6 Ar IR Kauffman, Hauge, et al., 1984

Notes

UUpper bound
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kinsey-Nielsen, Brazier, et al., 1986
Kinsey-Nielsen, S.; Brazier, C.R.; Bernath, P.F., Rotational analysis of the B 2Σ+--X 2Σ+ transition of BaOH and BaOD, J. Chem. Phys., 1986, 84, 2, 698, https://doi.org/10.1063/1.450566 . [all data]

Fernando, Douay, et al., 1990
Fernando, W.T.M.L.; Douay, M.; Bernath, P.F., Vibrational analysis of the and transitions of BaOH and BaOD, J. Mol. Spectrosc., 1990, 144, 2, 344, https://doi.org/10.1016/0022-2852(90)90220-K . [all data]

Tandy, Wang, et al., 2009
Tandy, J.D.; Wang, J.-G.; Bernth, P.F., High-resolution laser spectroscopy of BaOH and BaOD: Anomalous spin-orbit coupling in the state, J. Mol. Spectrosc., 2009, 255, 1, 63, https://doi.org/10.1016/j.jms.2009.03.002 . [all data]

Tandy, Wang, et al., 2011
Tandy, J.D.; Wang, J.-G.; Lievin, J.; Bernath, P.F., Investigating the electronic states of BaOH by V-type double resonance spectroscopy and ab initio calculations: Further evidence of perturbation from the state, J. Mol. Spectrosc., 2011, 270, 1, 44, https://doi.org/10.1016/j.jms.2011.08.009 . [all data]

Kauffman, Hauge, et al., 1984
Kauffman, J.W.; Hauge, R.H.; Margrave, J.L., High Temp. Sci., 1984, 18, 97. [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References