ND2
- Formula: D2N
- Molecular weight: 18.0349
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
gas | A-X | 500 | 680 | Dressler and Ramsay, 1959 | |||
Duxbury and Reid, 2007 | |||||||
Ar | A-X | 380 | 825 | Blindauer, Peric, et al., 1993 | |||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | Sym. stretch | 2520 | T | gas | AB | Dressler and Ramsay, 1959 |
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 2 | Bend | 1108.75 | gas | LMR | Hills and McKellar, 1979 Muenchausen, Hills, et al., 1985 | |
2 | Bend | 1110 | m | N2 | IR | Milligan and Jacox, 1965 | |
Notes
m | Medium |
T | Tentative assignment or approximate value |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dressler and Ramsay, 1959
Dressler, K.; Ramsay, D.A.,
The Electronic Absorption Spectra of NHFormula and NDFormula,
Phil. Trans. Roy. Soc. (London) A251, 1959, 251, 1002, 553, https://doi.org/10.1098/rsta.1959.0011
. [all data]
Duxbury and Reid, 2007
Duxbury, G.; Reid, J.P.,
Renner--Teller interaction, high angular momentum states and spin-orbit interaction in the electronic spectrum of ND,
Mol. Phys., 2007, 105, 11-12, 1603, https://doi.org/10.1080/00268970701384480
. [all data]
Blindauer, Peric, et al., 1993
Blindauer, C.; Peric, M.; Schurath, U.,
The Visible Absorption Spectrum of Matrix-Isolated NH2 and Its Deuterides - Comparison with Calculated Spectroscopic Properties,
J. Mol. Spectrosc., 1993, 158, 1, 177, https://doi.org/10.1006/jmsp.1993.1065
. [all data]
Hills and McKellar, 1979
Hills, G.W.; McKellar, A.R.W.,
Laser magnetic resonance spectrum of the ν2 band of ND2,
J. Chem. Phys., 1979, 71, 8, 3330, https://doi.org/10.1063/1.438775
. [all data]
Muenchausen, Hills, et al., 1985
Muenchausen, R.E.; Hills, G.W.; Merienne-Lafore, M.F.; Ramsay, D.A.; Vervloet, M.; Birss, F.W.,
Further studies of the electronic and vibrational spectra of ND2,
J. Mol. Spectrosc., 1985, 112, 1, 203, https://doi.org/10.1016/0022-2852(85)90204-8
. [all data]
Milligan and Jacox, 1965
Milligan, D.E.; Jacox, M.E.,
Matrix-Isolation Infrared Spectrum of the Free Radical NH2,
J. Chem. Phys., 1965, 43, 12, 4487, https://doi.org/10.1063/1.1696721
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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