(cyc-O2V)O2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16140 ± 800 gas Wu and Wang, 1998

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 11300 ± 800 gas Wu and Wang, 1998

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 8070 ± 800 gas Wu and Wang, 1998

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
OO stretch 1121.9 Ar IR Chertihin, Bare, et al., 1997
OO stretch 1126.4 N2 IR Chertihin, Bare, et al., 1997
OVO s-stretch 975.3 Ar IR Chertihin, Bare, et al., 1997
OVO a-stretch 974.1 s Ar IR Chertihin, Bare, et al., 1997
OVO a-stretch 968.8 N2 IR Chertihin, Bare, et al., 1997
555.6 Ar IR Chertihin, Bare, et al., 1997
561.8 N2 IR Chertihin, Bare, et al., 1997
506.9 Ar IR Chertihin, Bare, et al., 1997
Zhou and Andrews, 1998

Additional references: Jacox, 2003, page 296

Notes

sStrong
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu and Wang, 1998
Wu, H.; Wang, L.-S., A Photoelectron Spectroscopic Study of Monovanadium Oxide Anions (VOx-, x=1-4), J. Phys. Chem., 1998, 108, 13, 5310, https://doi.org/10.1063/1.475966 . [all data]

Chertihin, Bare, et al., 1997
Chertihin, G.V.; Bare, W.D.; Andrews, L., Reactions of Laser-Ablated Vanadium Atoms with Dioxygen. Infrared Spectra of VO, VO, J. Phys. Chem. A, 1997, 101, 28, 5090, https://doi.org/10.1021/jp970559u . [all data]

Zhou and Andrews, 1998
Zhou, M.; Andrews, L., Reactions of Laser-Ablated Niobium and Tantalum Atoms with Oxygen Molecules: Infrared Spectra of Niobium and Tantalum Oxide Molecules, Anions, and Cations, J. Phys. Chem. A, 1998, 102, 43, 8251, https://doi.org/10.1021/jp982212c . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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