OVO-


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Td = 16380 ± 80 gas Wu and Wang, 1998

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 2500 ± 80 T gas Wu and Wang, 1998

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

b2 3 Asym. stretch 896.9 Ar IR Chertihin, Bare, et al., 1997
3 Asym. stretch 894.3 Ar IR Chertihin, Bare, et al., 1997

Additional references: Jacox, 2003, page 117

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu and Wang, 1998
Wu, H.; Wang, L.-S., A Photoelectron Spectroscopic Study of Monovanadium Oxide Anions (VOx-, x=1-4), J. Phys. Chem., 1998, 108, 13, 5310, https://doi.org/10.1063/1.475966 . [all data]

Chertihin, Bare, et al., 1997
Chertihin, G.V.; Bare, W.D.; Andrews, L., Reactions of Laser-Ablated Vanadium Atoms with Dioxygen. Infrared Spectra of VO, VO, J. Phys. Chem. A, 1997, 101, 28, 5090, https://doi.org/10.1021/jp970559u . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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