cyc-NiO2
- Formula: NiO2
- Molecular weight: 90.6922
- Information on this page:
- Options:
Vibrational and/or electronic energy levels
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| To = 8000 | T | gas | Wu and Wang, 1997 | ||||
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a1 | 1 | OO stretch | 968.4 | Ne | IR | Allouti, Manceron, et al., 2006 | |
| 1 | OO stretch | 967.1 | s | Ar | IR | Huber, Klotzbucher, et al., 1973 Citra, Chertihin, et al., 1997 Danset, Manceron, et al., 2001 | |
| 1 | OO stretch | 970.1 | N2 | IR | Citra, Chertihin, et al., 1997 | ||
| 2 | ONiO s-stretch | 541.6 | Ne | IR | Allouti, Manceron, et al., 2006 | ||
| 2 | NiO s-stretch | 538.3 | w | Ar | IR | Citra, Chertihin, et al., 1997 Danset, Manceron, et al., 2001 | |
| b2 | 3 | ONiO a-stretch | 499.1 | Ne | IR | Allouti, Manceron, et al., 2006 | |
| 3 | NiO a-stretch | 511.7 | m | Ar | IR | Citra, Chertihin, et al., 1997 Danset, Manceron, et al., 2001 | |
Additional references: Jacox, 1998, page 177; Jacox, 2003, page 107
Notes
| w | Weak |
| m | Medium |
| s | Strong |
| T | Tentative assignment or approximate value |
| o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wu and Wang, 1997
Wu, H.; Wang, L.-S.,
A Study of Nickel Monoxide (NiO), Nickel Dioxide (NiO2) and Ni(O2) Complex by Anion Photoelectron Spectroscopy,
J. Chem. Phys., 1997, 107, 1, 16, https://doi.org/10.1063/1.474362
. [all data]
Allouti, Manceron, et al., 2006
Allouti, F.; Manceron, L.; Alikhani, M.E.,
The Ni + O2 reaction: A combined IR matrix isolation and theoretical study of the formation and structure of NiO2,
Phys. Chem. Chem. Phys., 2006, 8, 4, 448, https://doi.org/10.1039/b513038g
. [all data]
Huber, Klotzbucher, et al., 1973
Huber, H.; Klotzbucher, W.; Ozin, G.A.; Vander Voet, A.,
Binary Dioxygen Complexes of Nickel, Palladium, and Platinum, M(O,
Can J. Chem., 1973, 51, 16, 2722, https://doi.org/10.1139/v73-408
. [all data]
Citra, Chertihin, et al., 1997
Citra, A.; Chertihin, G.V.; Andrews, L.; Neurock, M.,
Reactions of Laser-Ablated Nickel Atoms with Dioxygen. Infrared Spectra and Density Functional Calculations of Nickel Oxides NiO, ONiO, Ni,
J. Phys. Chem. A, 1997, 101, 17, 3109, https://doi.org/10.1021/jp970019x
. [all data]
Danset, Manceron, et al., 2001
Danset, D.; Manceron, L.; Andrews, L.,
Vibrational Spectra of Nickel and Platinum Dioxide Molecules Isolated in Solid Argon,
J. Phys. Chem. A, 2001, 105, 30, 7205, https://doi.org/10.1021/jp010605x
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.