HXeI
- Formula: HIXe
- Molecular weight: 259.205
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| Tx = 31750 | Xe | Ahokas, Vaskonen, et al., 2000 | |||||
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 1 | HXe stretch | 1193 | vs | Xe | IR | Pettersson, Lundell, et al., 1995 Pettersson, Nieminen, et al., 1997 Lundell, Pettersson, et al., 2000 Ahokas, Vaskonen, et al., 2000 |
| Π | 2 | Bend | 450 | w | Xe | IR | Pettersson, Lundell, et al., 1995 Lundell, Pettersson, et al., 2000 |
| Σ+ | 3 | XeI stretch | 146 | T | Xe | IR | Lundell, Pettersson, et al., 2000 |
Additional references: Jacox, 1998, page 158; Jacox, 2003, page 48
Notes
| w | Weak |
| vs | Very strong |
| T | Tentative assignment or approximate value |
| x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ahokas, Vaskonen, et al., 2000
Ahokas, J.; Vaskonen, K.; Eloranta, J.; Kunttu, H.,
Electronic Absorption Spectra of HXeCl, HXeBr, HXeI, and HXeCN in Xe Matrix,
J. Phys. Chem. A, 2000, 104, 42, 9506, https://doi.org/10.1021/jp002141t
. [all data]
Pettersson, Lundell, et al., 1995
Pettersson, M.; Lundell, J.; Rasanen, M.,
Neutral rare-gas containing charge-transfer molecules in solid matrices. I. HXeCl, HXeBr, HXeI, and HKrCl in Kr and Xe,
J. Chem. Phys., 1995, 102, 16, 6423, https://doi.org/10.1063/1.469357
. [all data]
Pettersson, Nieminen, et al., 1997
Pettersson, M.; Nieminen, J.; Khriachtchev, L.; Rasanen, M.,
The mechanism of formation and infrared-induced decomposition of HXeI in solid Xe,
J. Chem. Phys., 1997, 107, 20, 8423, https://doi.org/10.1063/1.475042
. [all data]
Lundell, Pettersson, et al., 2000
Lundell, J.; Pettersson, M.; Khriachtchev, L.; Rasanen, M.; Chaban, G.M.; Gerber, R.B.,
Infrared spectrum of HXeI revisited: anharmonic vibrational calculations and matrix isolation experiments,
Chem. Phys. Lett., 2000, 322, 5, 389, https://doi.org/10.1016/S0009-2614(00)00444-9
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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