H2GaNH2

Formula: GaH₄N
Molecular weight: 87.761
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Vibrational and/or electronic energy levels

State: X

Vib. sym.	No.	Approximate type of mode	cm^-1		Med.	Method	References


a₁	1	NH₂ s-stretch	3413.4		Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2
	2	GaH₂ s-stretch	1970.8	T	Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2
	3	NH₂ scissors	1530.4		Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2
	4	GaH₂ scissors	779.6		Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2
	5	GaN stretch	706.2		Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2
b₁	7	GaH₂ OPLA	567.7		Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2
	8	NH₂ OPLA	304.9		Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2
b₂	j 9	NH₂ a-stretch	3510.7		Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2
	10	GaH₂ a-stretch	1970.8	T	Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2
	11	NH₂ rock	782.8		Ar	IR	Himmel, Downs, et al., 2000 Himmel, Downs, et al., 2000, 2

Additional references: Jacox, 2003, page 310

Notes

Tentative assignment or approximate value

References

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Himmel, Downs, et al., 2000
Himmel, H.-J.; Downs, A.J.; Greene, T.M., Chem. Commun., 2000, 871. [all data]

Himmel, Downs, et al., 2000, 2
Himmel, H.-J.; Downs, A.J.; Greene, T.M., Thermal and Photochemical Reactions of Aluminum, Gallium, and Indium Atoms (M) in the Presence of Ammonia: Generation and Characterization of the Species M·NH, J. Am. Chem. Soc., 2000, 122, 40, 9793, https://doi.org/10.1021/ja001313x . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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