GaNH3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 22730 Ar Himmel, Downs, et al., 2000
Himmel, Downs, et al., 2000, 2

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 NH3 a-stretch 3441.5 Ar IR Himmel, Downs, et al., 2000, 2
4 NH3 umbrella 1104.2 Ar IR Himmel, Downs, et al., 2000
Himmel, Downs, et al., 2000, 2
6 GaN stretch 161 gas TPE Li, Rothschopf, et al., 2001
a 8 NH3 a-deform. 1580.7 Ar IR Himmel, Downs, et al., 2000, 2

Additional references: Jacox, 2003, page 252

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Himmel, Downs, et al., 2000
Himmel, H.-J.; Downs, A.J.; Greene, T.M., Chem. Commun., 2000, 871. [all data]

Himmel, Downs, et al., 2000, 2
Himmel, H.-J.; Downs, A.J.; Greene, T.M., Thermal and Photochemical Reactions of Aluminum, Gallium, and Indium Atoms (M) in the Presence of Ammonia: Generation and Characterization of the Species M·NH, J. Am. Chem. Soc., 2000, 122, 40, 9793, https://doi.org/10.1021/ja001313x . [all data]

Li, Rothschopf, et al., 2001
Li, S.; Rothschopf, G.K.; Pillai, D.; Sohnlein, B.R.; Wilson, B.M.; Yang, D.-S., Spectroscopy and calculations of weakly bound gallium complexes with ammonia and monomethylamine, J. Chem. Phys., 2001, 115, 17, 7968, https://doi.org/10.1063/1.1410973 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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